Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV)

The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol­ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C—Sn—C = 124.82 (8) and 137.69 (8)°]. The Cl atom of the mol­ecule with the small...

Descripción completa

Detalles Bibliográficos
Autores principales: Vafaee, Maryam, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007514/
https://www.ncbi.nlm.nih.gov/pubmed/21588190
http://dx.doi.org/10.1107/S1600536810027790
_version_ 1782194375968686080
author Vafaee, Maryam
Amini, Mostafa M.
Ng, Seik Weng
author_facet Vafaee, Maryam
Amini, Mostafa M.
Ng, Seik Weng
author_sort Vafaee, Maryam
collection PubMed
description The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol­ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C—Sn—C = 124.82 (8) and 137.69 (8)°]. The Cl atom of the mol­ecule with the smaller C—Sn—C angle inter­acts weakly with the Sn(IV) atom of the mol­ecule with the wider C—Sn—C angle at an Sn⋯Cl distance of 3.595 (1) Å. Weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonding is present in the crystal structure.
format Text
id pubmed-3007514
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30075142010-12-30 Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV) Vafaee, Maryam Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol­ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C—Sn—C = 124.82 (8) and 137.69 (8)°]. The Cl atom of the mol­ecule with the smaller C—Sn—C angle inter­acts weakly with the Sn(IV) atom of the mol­ecule with the wider C—Sn—C angle at an Sn⋯Cl distance of 3.595 (1) Å. Weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007514/ /pubmed/21588190 http://dx.doi.org/10.1107/S1600536810027790 Text en © Vafaee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vafaee, Maryam
Amini, Mostafa M.
Ng, Seik Weng
Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV)
title Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV)
title_full Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV)
title_fullStr Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV)
title_full_unstemmed Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV)
title_short Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV)
title_sort chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) n,o)phenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007514/
https://www.ncbi.nlm.nih.gov/pubmed/21588190
http://dx.doi.org/10.1107/S1600536810027790
work_keys_str_mv AT vafaeemaryam chloridomethyl2methylquinolin8olatok2nophenyltiniv
AT aminimostafam chloridomethyl2methylquinolin8olatok2nophenyltiniv
AT ngseikweng chloridomethyl2methylquinolin8olatok2nophenyltiniv

Ejemplares similares