Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late

The title compound, C(15)H(13)Br(4)NO(4), was obtained via radical bromination reaction of ethyl 6,7-dimeth­oxy-2-methyl­quinoline-3-carboxyl­ate and N-bromo­succinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar...

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Detalles Bibliográficos
Autores principales: Zhou, Ting, Long, Yu-hua, Yang, Ding-qiao, Zhang, Han-mei, Wang, Wen-ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007515/
https://www.ncbi.nlm.nih.gov/pubmed/21588439
http://dx.doi.org/10.1107/S1600536810029351
Descripción
Sumario:The title compound, C(15)H(13)Br(4)NO(4), was obtained via radical bromination reaction of ethyl 6,7-dimeth­oxy-2-methyl­quinoline-3-carboxyl­ate and N-bromo­succinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maximum deviation from the mean plane of 0.035 (1) Å. The dihedral angle between the six-membered rings is 2.33 (2)°. The meth­oxy O atoms of the two neighboring meth­oxy groups are in-plane while their methyl C atoms are located on either side of the quinolyl ring plane at distances of −1.207 (1) and 1.223 (1) Å.

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