Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late

The title compound, C(15)H(13)Br(4)NO(4), was obtained via radical bromination reaction of ethyl 6,7-dimeth­oxy-2-methyl­quinoline-3-carboxyl­ate and N-bromo­succinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar...

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Detalles Bibliográficos
Autores principales: Zhou, Ting, Long, Yu-hua, Yang, Ding-qiao, Zhang, Han-mei, Wang, Wen-ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007515/
https://www.ncbi.nlm.nih.gov/pubmed/21588439
http://dx.doi.org/10.1107/S1600536810029351
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author Zhou, Ting
Long, Yu-hua
Yang, Ding-qiao
Zhang, Han-mei
Wang, Wen-ling
author_facet Zhou, Ting
Long, Yu-hua
Yang, Ding-qiao
Zhang, Han-mei
Wang, Wen-ling
author_sort Zhou, Ting
collection PubMed
description The title compound, C(15)H(13)Br(4)NO(4), was obtained via radical bromination reaction of ethyl 6,7-dimeth­oxy-2-methyl­quinoline-3-carboxyl­ate and N-bromo­succinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maximum deviation from the mean plane of 0.035 (1) Å. The dihedral angle between the six-membered rings is 2.33 (2)°. The meth­oxy O atoms of the two neighboring meth­oxy groups are in-plane while their methyl C atoms are located on either side of the quinolyl ring plane at distances of −1.207 (1) and 1.223 (1) Å.
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spelling pubmed-30075152010-12-30 Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late Zhou, Ting Long, Yu-hua Yang, Ding-qiao Zhang, Han-mei Wang, Wen-ling Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(13)Br(4)NO(4), was obtained via radical bromination reaction of ethyl 6,7-dimeth­oxy-2-methyl­quinoline-3-carboxyl­ate and N-bromo­succinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maximum deviation from the mean plane of 0.035 (1) Å. The dihedral angle between the six-membered rings is 2.33 (2)°. The meth­oxy O atoms of the two neighboring meth­oxy groups are in-plane while their methyl C atoms are located on either side of the quinolyl ring plane at distances of −1.207 (1) and 1.223 (1) Å. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007515/ /pubmed/21588439 http://dx.doi.org/10.1107/S1600536810029351 Text en © Zhou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Ting
Long, Yu-hua
Yang, Ding-qiao
Zhang, Han-mei
Wang, Wen-ling
Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late
title Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late
title_full Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late
title_fullStr Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late
title_full_unstemmed Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late
title_short Ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late
title_sort ethyl 5,8-dibromo-2-dibromo­methyl-6,7-dimeth­oxyquinoline-3-carb­oxy­late
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007515/
https://www.ncbi.nlm.nih.gov/pubmed/21588439
http://dx.doi.org/10.1107/S1600536810029351
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AT longyuhua ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate
AT yangdingqiao ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate
AT zhanghanmei ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate
AT wangwenling ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate

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