Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate

The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra­aza­cyclo­tetra­decane (cyclam) ligand and is coordinated by two water mol­ecules in a Jahn–Teller-type tetra­gonally distorted octa­hedral geometry. The...

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Autores principales: Ahmad Tajidi, Nur Syamimi, Abdullah, Norbani, Arifin, Zainudin, Tan, Kong Wai, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007516/
https://www.ncbi.nlm.nih.gov/pubmed/21588134
http://dx.doi.org/10.1107/S1600536810025705
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author Ahmad Tajidi, Nur Syamimi
Abdullah, Norbani
Arifin, Zainudin
Tan, Kong Wai
Ng, Seik Weng
author_facet Ahmad Tajidi, Nur Syamimi
Abdullah, Norbani
Arifin, Zainudin
Tan, Kong Wai
Ng, Seik Weng
author_sort Ahmad Tajidi, Nur Syamimi
collection PubMed
description The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra­aza­cyclo­tetra­decane (cyclam) ligand and is coordinated by two water mol­ecules in a Jahn–Teller-type tetra­gonally distorted octa­hedral geometry. The Cu(II) atom lies on a center of inversion. The cations, anions and uncoordinated water mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming a layer structure parallel to (001).
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spelling pubmed-30075162010-12-30 Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate Ahmad Tajidi, Nur Syamimi Abdullah, Norbani Arifin, Zainudin Tan, Kong Wai Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra­aza­cyclo­tetra­decane (cyclam) ligand and is coordinated by two water mol­ecules in a Jahn–Teller-type tetra­gonally distorted octa­hedral geometry. The Cu(II) atom lies on a center of inversion. The cations, anions and uncoordinated water mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming a layer structure parallel to (001). International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007516/ /pubmed/21588134 http://dx.doi.org/10.1107/S1600536810025705 Text en © Ahmad Tajidi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ahmad Tajidi, Nur Syamimi
Abdullah, Norbani
Arifin, Zainudin
Tan, Kong Wai
Ng, Seik Weng
Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate
title Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate
title_full Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate
title_fullStr Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate
title_full_unstemmed Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate
title_short Diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N (1),N (4),N (8),N (11))copper(II) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate
title_sort diaqua­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) n (1),n (4),n (8),n (11))copper(ii) bis­(2,3,4,5,6-penta­fluoro­benzoate) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007516/
https://www.ncbi.nlm.nih.gov/pubmed/21588134
http://dx.doi.org/10.1107/S1600536810025705
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