Tetra­ethyl­ammonium tricarbonyl­chlorido(quinoxaline-2-carboxyl­ato-κ(2) N (1),O)rhenate(I)

In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C—H⋯O hydrogen bond...

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Detalles Bibliográficos
Autores principales: Suthiram, Janine, Zeevaart, Jan Rijn, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007518/
https://www.ncbi.nlm.nih.gov/pubmed/21588112
http://dx.doi.org/10.1107/S160053681002893X
Descripción
Sumario:In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C—H⋯O hydrogen bonding and π–π stacking inter­actions involving the benzene rings, with a centroid–centroid distance of 3.4220 (1) Å.

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