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Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2) N (1),O)rhenate(I)
In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C—H⋯O hydrogen bond...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007518/ https://www.ncbi.nlm.nih.gov/pubmed/21588112 http://dx.doi.org/10.1107/S160053681002893X |
| _version_ | 1782194377048719360 |
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| author | Suthiram, Janine Zeevaart, Jan Rijn Visser, Hendrik G. Roodt, Andreas |
| author_facet | Suthiram, Janine Zeevaart, Jan Rijn Visser, Hendrik G. Roodt, Andreas |
| author_sort | Suthiram, Janine |
| collection | PubMed |
| description | In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C—H⋯O hydrogen bonding and π–π stacking interactions involving the benzene rings, with a centroid–centroid distance of 3.4220 (1) Å. |
| format | Text |
| id | pubmed-3007518 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30075182010-12-30 Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2) N (1),O)rhenate(I) Suthiram, Janine Zeevaart, Jan Rijn Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C—H⋯O hydrogen bonding and π–π stacking interactions involving the benzene rings, with a centroid–centroid distance of 3.4220 (1) Å. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007518/ /pubmed/21588112 http://dx.doi.org/10.1107/S160053681002893X Text en © Suthiram et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Suthiram, Janine Zeevaart, Jan Rijn Visser, Hendrik G. Roodt, Andreas Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2) N (1),O)rhenate(I) |
| title | Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2)
N
(1),O)rhenate(I) |
| title_full | Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2)
N
(1),O)rhenate(I) |
| title_fullStr | Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2)
N
(1),O)rhenate(I) |
| title_full_unstemmed | Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2)
N
(1),O)rhenate(I) |
| title_short | Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2)
N
(1),O)rhenate(I) |
| title_sort | tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ(2)
n
(1),o)rhenate(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007518/ https://www.ncbi.nlm.nih.gov/pubmed/21588112 http://dx.doi.org/10.1107/S160053681002893X |
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