Poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(I)]

In the crystal structure of the title compound, [Ag(C(7)H(3)N(2)O(2)S)](n), the Ag(I) atom is coordinated by two N atoms and three O atoms of four organic ligands forming a distorted square pyramid. The carboxyl­ate group acts as a bidentate ligand on one Ag(I) atom and as a bridging group for a sym...

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Detalles Bibliográficos
Autores principales: Zhao, Jiong-Peng, Liu, Fu-Chen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007519/
https://www.ncbi.nlm.nih.gov/pubmed/21588198
http://dx.doi.org/10.1107/S1600536810027029
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author Zhao, Jiong-Peng
Liu, Fu-Chen
author_facet Zhao, Jiong-Peng
Liu, Fu-Chen
author_sort Zhao, Jiong-Peng
collection PubMed
description In the crystal structure of the title compound, [Ag(C(7)H(3)N(2)O(2)S)](n), the Ag(I) atom is coordinated by two N atoms and three O atoms of four organic ligands forming a distorted square pyramid. The carboxyl­ate group acts as a bidentate ligand on one Ag(I) atom and as a bridging group for a symmetry-related Ag(I) atom, forming a dimer. Futhermore, the two N atoms of two thia­diazole rings bridge a third symmetry-related Ag(I) atom, forming a six-membered ring. These two frameworks, AgO(2)Ag and AgN(4)Ag, extend in three directions, forming a three-dimensionnal polymer. The whole polymer is organized around inversion centers.
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spelling pubmed-30075192010-12-30 Poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(I)] Zhao, Jiong-Peng Liu, Fu-Chen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ag(C(7)H(3)N(2)O(2)S)](n), the Ag(I) atom is coordinated by two N atoms and three O atoms of four organic ligands forming a distorted square pyramid. The carboxyl­ate group acts as a bidentate ligand on one Ag(I) atom and as a bridging group for a symmetry-related Ag(I) atom, forming a dimer. Futhermore, the two N atoms of two thia­diazole rings bridge a third symmetry-related Ag(I) atom, forming a six-membered ring. These two frameworks, AgO(2)Ag and AgN(4)Ag, extend in three directions, forming a three-dimensionnal polymer. The whole polymer is organized around inversion centers. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007519/ /pubmed/21588198 http://dx.doi.org/10.1107/S1600536810027029 Text en © Zhao and Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Jiong-Peng
Liu, Fu-Chen
Poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(I)]
title Poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(I)]
title_full Poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(I)]
title_fullStr Poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(I)]
title_full_unstemmed Poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(I)]
title_short Poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(I)]
title_sort poly[(μ(4)-1,2,3-benzothia­diazole-7-carboxyl­ato)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007519/
https://www.ncbi.nlm.nih.gov/pubmed/21588198
http://dx.doi.org/10.1107/S1600536810027029
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