1-[(2,3,4,5,6-Penta­fluoro­phen­yl)ethyn­yl]ferrocene

The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(13)H(4)F(5))], consists of a ferrocenyl group and a 2,3,4,5,6-penta­fluoro­benzene group linked through an ethyne spacer. The crystal packing is dominated by inter­molecular C—H⋯F hydrogen bonds, C—F⋯π inter­actions between the penta­fl...

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Detalles Bibliográficos
Autores principales: Zhang, Chan, Zhang, Honglin, Dai, Dongdong, Liang, Jinhua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007523/
https://www.ncbi.nlm.nih.gov/pubmed/21588152
http://dx.doi.org/10.1107/S1600536810026772
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author Zhang, Chan
Zhang, Honglin
Dai, Dongdong
Liang, Jinhua
author_facet Zhang, Chan
Zhang, Honglin
Dai, Dongdong
Liang, Jinhua
author_sort Zhang, Chan
collection PubMed
description The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(13)H(4)F(5))], consists of a ferrocenyl group and a 2,3,4,5,6-penta­fluoro­benzene group linked through an ethyne spacer. The crystal packing is dominated by inter­molecular C—H⋯F hydrogen bonds, C—F⋯π inter­actions between the penta­fluoro­benzene groups [F⋯centroid distances = 3.882 (2) and 3.884 (2) Å] and π–π inter­actions between the penta­fluoro­benzene and cyclo­penta­dienyl rings [centroid–centroid distance = 3.741 (1) Å].
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spelling pubmed-30075232010-12-30 1-[(2,3,4,5,6-Penta­fluoro­phen­yl)ethyn­yl]ferrocene Zhang, Chan Zhang, Honglin Dai, Dongdong Liang, Jinhua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(13)H(4)F(5))], consists of a ferrocenyl group and a 2,3,4,5,6-penta­fluoro­benzene group linked through an ethyne spacer. The crystal packing is dominated by inter­molecular C—H⋯F hydrogen bonds, C—F⋯π inter­actions between the penta­fluoro­benzene groups [F⋯centroid distances = 3.882 (2) and 3.884 (2) Å] and π–π inter­actions between the penta­fluoro­benzene and cyclo­penta­dienyl rings [centroid–centroid distance = 3.741 (1) Å]. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007523/ /pubmed/21588152 http://dx.doi.org/10.1107/S1600536810026772 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Chan
Zhang, Honglin
Dai, Dongdong
Liang, Jinhua
1-[(2,3,4,5,6-Penta­fluoro­phen­yl)ethyn­yl]ferrocene
title 1-[(2,3,4,5,6-Penta­fluoro­phen­yl)ethyn­yl]ferrocene
title_full 1-[(2,3,4,5,6-Penta­fluoro­phen­yl)ethyn­yl]ferrocene
title_fullStr 1-[(2,3,4,5,6-Penta­fluoro­phen­yl)ethyn­yl]ferrocene
title_full_unstemmed 1-[(2,3,4,5,6-Penta­fluoro­phen­yl)ethyn­yl]ferrocene
title_short 1-[(2,3,4,5,6-Penta­fluoro­phen­yl)ethyn­yl]ferrocene
title_sort 1-[(2,3,4,5,6-penta­fluoro­phen­yl)ethyn­yl]ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007523/
https://www.ncbi.nlm.nih.gov/pubmed/21588152
http://dx.doi.org/10.1107/S1600536810026772
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AT zhanghonglin 123456pentafluorophenylethynylferrocene
AT daidongdong 123456pentafluorophenylethynylferrocene
AT liangjinhua 123456pentafluorophenylethynylferrocene

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