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catena-Poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]

In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta­coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5′-dimethyl-2,2′-bipyridine (dbp) ligand and two O atoms of two different 2,2′-oxydibenzoic (odb) ligands occupy the basal plane wh...

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Detalles Bibliográficos
Autores principales: Mei, Chong-Zhen, Xiong, Han-Lin, Zhang, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007526/
https://www.ncbi.nlm.nih.gov/pubmed/21588146
http://dx.doi.org/10.1107/S160053681002622X
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author Mei, Chong-Zhen
Xiong, Han-Lin
Zhang, Peng
author_facet Mei, Chong-Zhen
Xiong, Han-Lin
Zhang, Peng
author_sort Mei, Chong-Zhen
collection PubMed
description In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta­coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5′-dimethyl-2,2′-bipyridine (dbp) ligand and two O atoms of two different 2,2′-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518 (11) Å and the Cu atom is displaced by 0.1507 (11) Å from this plane towards the apical water O atom. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional supra­molecular structure.
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spelling pubmed-30075262010-12-30 catena-Poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′] Mei, Chong-Zhen Xiong, Han-Lin Zhang, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta­coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5′-dimethyl-2,2′-bipyridine (dbp) ligand and two O atoms of two different 2,2′-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518 (11) Å and the Cu atom is displaced by 0.1507 (11) Å from this plane towards the apical water O atom. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional supra­molecular structure. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007526/ /pubmed/21588146 http://dx.doi.org/10.1107/S160053681002622X Text en © Mei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mei, Chong-Zhen
Xiong, Han-Lin
Zhang, Peng
catena-Poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]
title catena-Poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]
title_full catena-Poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]
title_fullStr catena-Poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]
title_short catena-Poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]
title_sort catena-poly[[aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) n,n′)copper(ii)]-μ-2,2′-oxydibenzoato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007526/
https://www.ncbi.nlm.nih.gov/pubmed/21588146
http://dx.doi.org/10.1107/S160053681002622X
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