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catena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]
In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is pentacoordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5′-dimethyl-2,2′-bipyridine (dbp) ligand and two O atoms of two different 2,2′-oxydibenzoic (odb) ligands occupy the basal plane wh...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007526/ https://www.ncbi.nlm.nih.gov/pubmed/21588146 http://dx.doi.org/10.1107/S160053681002622X |
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author | Mei, Chong-Zhen Xiong, Han-Lin Zhang, Peng |
author_facet | Mei, Chong-Zhen Xiong, Han-Lin Zhang, Peng |
author_sort | Mei, Chong-Zhen |
collection | PubMed |
description | In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is pentacoordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5′-dimethyl-2,2′-bipyridine (dbp) ligand and two O atoms of two different 2,2′-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518 (11) Å and the Cu atom is displaced by 0.1507 (11) Å from this plane towards the apical water O atom. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a two-dimensional supramolecular structure. |
format | Text |
id | pubmed-3007526 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30075262010-12-30 catena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′] Mei, Chong-Zhen Xiong, Han-Lin Zhang, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is pentacoordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5′-dimethyl-2,2′-bipyridine (dbp) ligand and two O atoms of two different 2,2′-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518 (11) Å and the Cu atom is displaced by 0.1507 (11) Å from this plane towards the apical water O atom. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a two-dimensional supramolecular structure. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007526/ /pubmed/21588146 http://dx.doi.org/10.1107/S160053681002622X Text en © Mei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mei, Chong-Zhen Xiong, Han-Lin Zhang, Peng catena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′] |
title |
catena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_full |
catena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_fullStr |
catena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_full_unstemmed |
catena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_short |
catena-Poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_sort | catena-poly[[aqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)copper(ii)]-μ-2,2′-oxydibenzoato-κ(2)
o:o′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007526/ https://www.ncbi.nlm.nih.gov/pubmed/21588146 http://dx.doi.org/10.1107/S160053681002622X |
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