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N-{4-[(3,4-Dimethyl­phen­yl)sulfamo­yl]phen­yl}acetamide

Two independent mol­ecules comprise the asymmetric unit of the title compound, C(16)H(18)N(2)O(3)S. Small but significant twists about the (S)N—C and S—C bonds differentiate the mol­ecules but the most obvious difference is found in the relative orientation of the meta-methyl groups, which lie on op...

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Detalles Bibliográficos
Autores principales: Khan, Islam Ullah, John, Peter, Khizar, Saima, Sharif, Shahzad, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007528/
https://www.ncbi.nlm.nih.gov/pubmed/21588423
http://dx.doi.org/10.1107/S1600536810029405
Descripción
Sumario:Two independent mol­ecules comprise the asymmetric unit of the title compound, C(16)H(18)N(2)O(3)S. Small but significant twists about the (S)N—C and S—C bonds differentiate the mol­ecules but the most obvious difference is found in the relative orientation of the meta-methyl groups, which lie on opposite sides of the mol­ecules. Overall, both mol­ecules adopt a U shape but with significant twisting evident, particularly in the second independent mol­ecule [dihedral angles between benzene rings = 63.90 (13) and 35.78 (11)°]. In the crystal, N—H⋯O hydrogen bonds lead to supra­molecular chains with a tubular topology propagating in [100] and C—H⋯O contacts cross-link the chains.