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4-Aminopyridinium 2-hydroxybenzoate
In the salicylate anion of the title salt, C(5)H(7)N(2) (+)·C(7)H(5)O(3) (−), an intramolecular O—H⋯O hydrogen bond generating an S(6) ring motif is observed. In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to the ab plane by N—H⋯O and C—H⋯O hydro...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007529/ https://www.ncbi.nlm.nih.gov/pubmed/21588323 http://dx.doi.org/10.1107/S1600536810027042 |
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author | Fun, Hoong-Kun Hemamalini, Madhukar Rajakannan, Venkatachalam |
author_facet | Fun, Hoong-Kun Hemamalini, Madhukar Rajakannan, Venkatachalam |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the salicylate anion of the title salt, C(5)H(7)N(2) (+)·C(7)H(5)O(3) (−), an intramolecular O—H⋯O hydrogen bond generating an S(6) ring motif is observed. In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to the ab plane by N—H⋯O and C—H⋯O hydrogen bonds. The network contains R (2) (2)(7) and R (1) (2)(4) ring motifs. Weak π–π interactions between the benzene and pyridinium rings [centroid–centroid distance = 3.688 (1) Å] are also observed. |
format | Text |
id | pubmed-3007529 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30075292010-12-30 4-Aminopyridinium 2-hydroxybenzoate Fun, Hoong-Kun Hemamalini, Madhukar Rajakannan, Venkatachalam Acta Crystallogr Sect E Struct Rep Online Organic Papers In the salicylate anion of the title salt, C(5)H(7)N(2) (+)·C(7)H(5)O(3) (−), an intramolecular O—H⋯O hydrogen bond generating an S(6) ring motif is observed. In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to the ab plane by N—H⋯O and C—H⋯O hydrogen bonds. The network contains R (2) (2)(7) and R (1) (2)(4) ring motifs. Weak π–π interactions between the benzene and pyridinium rings [centroid–centroid distance = 3.688 (1) Å] are also observed. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007529/ /pubmed/21588323 http://dx.doi.org/10.1107/S1600536810027042 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Hemamalini, Madhukar Rajakannan, Venkatachalam 4-Aminopyridinium 2-hydroxybenzoate |
title | 4-Aminopyridinium 2-hydroxybenzoate |
title_full | 4-Aminopyridinium 2-hydroxybenzoate |
title_fullStr | 4-Aminopyridinium 2-hydroxybenzoate |
title_full_unstemmed | 4-Aminopyridinium 2-hydroxybenzoate |
title_short | 4-Aminopyridinium 2-hydroxybenzoate |
title_sort | 4-aminopyridinium 2-hydroxybenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007529/ https://www.ncbi.nlm.nih.gov/pubmed/21588323 http://dx.doi.org/10.1107/S1600536810027042 |
work_keys_str_mv | AT funhoongkun 4aminopyridinium2hydroxybenzoate AT hemamalinimadhukar 4aminopyridinium2hydroxybenzoate AT rajakannanvenkatachalam 4aminopyridinium2hydroxybenzoate |