2,10-Bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene

The title compound, C(24)H(20)Br(2)N(2)O(4), is an 18-membered tricycle including two isoxazole rings. The asymmetric unit contains one half of the formula unit; a centre of inversion is located at the centroid of the compound. The dihedral angle between adjacent isoxazole and benzene rings is 84.0...

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Detalles Bibliográficos
Autores principales: Ha, Kwang, Park, Sae Byul, Lee, Young Ju, Kim, Hyung Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007534/
https://www.ncbi.nlm.nih.gov/pubmed/21588410
http://dx.doi.org/10.1107/S1600536810028813
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author Ha, Kwang
Park, Sae Byul
Lee, Young Ju
Kim, Hyung Jin
author_facet Ha, Kwang
Park, Sae Byul
Lee, Young Ju
Kim, Hyung Jin
author_sort Ha, Kwang
collection PubMed
description The title compound, C(24)H(20)Br(2)N(2)O(4), is an 18-membered tricycle including two isoxazole rings. The asymmetric unit contains one half of the formula unit; a centre of inversion is located at the centroid of the compound. The dihedral angle between adjacent isoxazole and benzene rings is 84.0 (2)°. The compound displays intra- and inter­molecular π–π stacking inter­actions between the isoxazole rings, the shortest centroid–centroid distances being 3.837 (3) and 3.634 (3) Å, respectively. The mol­ecules are stacked in columns along the a axis with short Br⋯Br contacts [3.508 (1) Å].
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spelling pubmed-30075342010-12-30 2,10-Bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene Ha, Kwang Park, Sae Byul Lee, Young Ju Kim, Hyung Jin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(20)Br(2)N(2)O(4), is an 18-membered tricycle including two isoxazole rings. The asymmetric unit contains one half of the formula unit; a centre of inversion is located at the centroid of the compound. The dihedral angle between adjacent isoxazole and benzene rings is 84.0 (2)°. The compound displays intra- and inter­molecular π–π stacking inter­actions between the isoxazole rings, the shortest centroid–centroid distances being 3.837 (3) and 3.634 (3) Å, respectively. The mol­ecules are stacked in columns along the a axis with short Br⋯Br contacts [3.508 (1) Å]. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007534/ /pubmed/21588410 http://dx.doi.org/10.1107/S1600536810028813 Text en © Ha et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ha, Kwang
Park, Sae Byul
Lee, Young Ju
Kim, Hyung Jin
2,10-Bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene
title 2,10-Bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene
title_full 2,10-Bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene
title_fullStr 2,10-Bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene
title_full_unstemmed 2,10-Bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene
title_short 2,10-Bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene
title_sort 2,10-bis(3-bromo­phen­yl)-3,7,11,15-tetra­oxa-8,16-diaza­tricyclo­[12.2.1.1(6,9)]octa­deca-1(16),6(18),8,14(17)-tetra­ene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007534/
https://www.ncbi.nlm.nih.gov/pubmed/21588410
http://dx.doi.org/10.1107/S1600536810028813
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