4-Chloro-N-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N—C bonds in the C—SO(2)—NH—C segment have gauche torsions with respect to the S=O bonds. Further, the conformation of the N—H bond is syn to the ortho-methyl group in the sulfonyl benzene ring. The torsion angle of the C—SO(2)—N...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007535/
https://www.ncbi.nlm.nih.gov/pubmed/21588314
http://dx.doi.org/10.1107/S1600536810026930
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author Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N—C bonds in the C—SO(2)—NH—C segment have gauche torsions with respect to the S=O bonds. Further, the conformation of the N—H bond is syn to the ortho-methyl group in the sulfonyl benzene ring. The torsion angle of the C—SO(2)—NH—C segment in the mol­ecule is 55.0 (2)°. The two benzene rings are tilted relative to each other by 67.0 (1)°. In the crystal, inter­molecular N–H⋯O hydrogen bonds link the mol­ecules into infinite column-like chains.
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spelling pubmed-30075352010-12-30 4-Chloro-N-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N—C bonds in the C—SO(2)—NH—C segment have gauche torsions with respect to the S=O bonds. Further, the conformation of the N—H bond is syn to the ortho-methyl group in the sulfonyl benzene ring. The torsion angle of the C—SO(2)—NH—C segment in the mol­ecule is 55.0 (2)°. The two benzene rings are tilted relative to each other by 67.0 (1)°. In the crystal, inter­molecular N–H⋯O hydrogen bonds link the mol­ecules into infinite column-like chains. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007535/ /pubmed/21588314 http://dx.doi.org/10.1107/S1600536810026930 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
4-Chloro-N-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title 4-Chloro-N-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_full 4-Chloro-N-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_fullStr 4-Chloro-N-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_full_unstemmed 4-Chloro-N-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_short 4-Chloro-N-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_sort 4-chloro-n-(4-chloro­phen­yl)-2-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007535/
https://www.ncbi.nlm.nih.gov/pubmed/21588314
http://dx.doi.org/10.1107/S1600536810026930
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AT fuesshartmut 4chloron4chlorophenyl2methylbenzenesulfonamide

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