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Di-μ-chlorido-bis­{chlorido[(R)/(S)-1,5-di­phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN (2)]zinc(II)}

In the centrosymmetric binuclear title compound, [Zn(2)Cl(4)(C(20)H(17)N(3))(2)], the coordination geometry of the Zn(II) ion can be described as a distorted ZnN(2)Cl(3) trigonal bipyramid (τ = 0.89), arising from the N,N′-bidentate ligand, a terminal chloride ion and two bridging chloride ions. The...

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Autores principales: Barceló-Oliver, Miquel, Terrón, Angel, García-Raso, Angel, Turel, Iztok, Morell, Marta
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007540/
https://www.ncbi.nlm.nih.gov/pubmed/21588142
http://dx.doi.org/10.1107/S1600536810026127
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author Barceló-Oliver, Miquel
Terrón, Angel
García-Raso, Angel
Turel, Iztok
Morell, Marta
author_facet Barceló-Oliver, Miquel
Terrón, Angel
García-Raso, Angel
Turel, Iztok
Morell, Marta
author_sort Barceló-Oliver, Miquel
collection PubMed
description In the centrosymmetric binuclear title compound, [Zn(2)Cl(4)(C(20)H(17)N(3))(2)], the coordination geometry of the Zn(II) ion can be described as a distorted ZnN(2)Cl(3) trigonal bipyramid (τ = 0.89), arising from the N,N′-bidentate ligand, a terminal chloride ion and two bridging chloride ions. The N atoms occupy one axial and one equatorial site and the terminal chloride ion occupies an equatorial site. The dihedral angle between the pyridine and pyrazole rings is 12.8 (2)°. In the crystal, aromatic π–π stacking [centroid–centroid separations = 3.812 (3) and 3.848 (3) Å] and C—H⋯Cl and C—H⋯π inter­actions help to establish the packing.
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spelling pubmed-30075402010-12-30 Di-μ-chlorido-bis­{chlorido[(R)/(S)-1,5-di­phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN (2)]zinc(II)} Barceló-Oliver, Miquel Terrón, Angel García-Raso, Angel Turel, Iztok Morell, Marta Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title compound, [Zn(2)Cl(4)(C(20)H(17)N(3))(2)], the coordination geometry of the Zn(II) ion can be described as a distorted ZnN(2)Cl(3) trigonal bipyramid (τ = 0.89), arising from the N,N′-bidentate ligand, a terminal chloride ion and two bridging chloride ions. The N atoms occupy one axial and one equatorial site and the terminal chloride ion occupies an equatorial site. The dihedral angle between the pyridine and pyrazole rings is 12.8 (2)°. In the crystal, aromatic π–π stacking [centroid–centroid separations = 3.812 (3) and 3.848 (3) Å] and C—H⋯Cl and C—H⋯π inter­actions help to establish the packing. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007540/ /pubmed/21588142 http://dx.doi.org/10.1107/S1600536810026127 Text en © Barceló-Oliver et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Barceló-Oliver, Miquel
Terrón, Angel
García-Raso, Angel
Turel, Iztok
Morell, Marta
Di-μ-chlorido-bis­{chlorido[(R)/(S)-1,5-di­phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN (2)]zinc(II)}
title Di-μ-chlorido-bis­{chlorido[(R)/(S)-1,5-di­phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN (2)]zinc(II)}
title_full Di-μ-chlorido-bis­{chlorido[(R)/(S)-1,5-di­phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN (2)]zinc(II)}
title_fullStr Di-μ-chlorido-bis­{chlorido[(R)/(S)-1,5-di­phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN (2)]zinc(II)}
title_full_unstemmed Di-μ-chlorido-bis­{chlorido[(R)/(S)-1,5-di­phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN (2)]zinc(II)}
title_short Di-μ-chlorido-bis­{chlorido[(R)/(S)-1,5-di­phenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN (2)]zinc(II)}
title_sort di-μ-chlorido-bis­{chlorido[(r)/(s)-1,5-di­phenyl-3-(2-pyridyl-κn)-2-pyrazoline-κn (2)]zinc(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007540/
https://www.ncbi.nlm.nih.gov/pubmed/21588142
http://dx.doi.org/10.1107/S1600536810026127
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