Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate

The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis­(di­phenyl­phosphan­yl)pentyl­amine ligands with an average Pt—P distance of 2.300 (1) Å. The coordination around the Pt(II) atom shows a highly distorted square-planar...

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Detalles Bibliográficos
Autores principales: Engelbrecht, Ilana, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007544/
https://www.ncbi.nlm.nih.gov/pubmed/21588157
http://dx.doi.org/10.1107/S1600536810025560
Descripción
Sumario:The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis­(di­phenyl­phosphan­yl)pentyl­amine ligands with an average Pt—P distance of 2.300 (1) Å. The coordination around the Pt(II) atom shows a highly distorted square-planar geometry, as evidenced by the P—Pt—P bite angles of 70.45 (3) and 70.64 (3)°. The asymmetric unit contains two hexa­fluoridophosphate ions, the metal complex and two dichloro­methane solvent mol­ecules. One of the chloride atoms of one of the dichloro­methane mol­ecules is disordered over two sites in a 0.515 (3):0.485 (3) ratio. C—H⋯F hydrogen bonds stabilize the crystal packing.

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