Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate

The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis­(di­phenyl­phosphan­yl)pentyl­amine ligands with an average Pt—P distance of 2.300 (1) Å. The coordination around the Pt(II) atom shows a highly distorted square-planar...

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Detalles Bibliográficos
Autores principales: Engelbrecht, Ilana, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007544/
https://www.ncbi.nlm.nih.gov/pubmed/21588157
http://dx.doi.org/10.1107/S1600536810025560
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author Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_facet Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_sort Engelbrecht, Ilana
collection PubMed
description The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis­(di­phenyl­phosphan­yl)pentyl­amine ligands with an average Pt—P distance of 2.300 (1) Å. The coordination around the Pt(II) atom shows a highly distorted square-planar geometry, as evidenced by the P—Pt—P bite angles of 70.45 (3) and 70.64 (3)°. The asymmetric unit contains two hexa­fluoridophosphate ions, the metal complex and two dichloro­methane solvent mol­ecules. One of the chloride atoms of one of the dichloro­methane mol­ecules is disordered over two sites in a 0.515 (3):0.485 (3) ratio. C—H⋯F hydrogen bonds stabilize the crystal packing.
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spelling pubmed-30075442010-12-30 Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis­(di­phenyl­phosphan­yl)pentyl­amine ligands with an average Pt—P distance of 2.300 (1) Å. The coordination around the Pt(II) atom shows a highly distorted square-planar geometry, as evidenced by the P—Pt—P bite angles of 70.45 (3) and 70.64 (3)°. The asymmetric unit contains two hexa­fluoridophosphate ions, the metal complex and two dichloro­methane solvent mol­ecules. One of the chloride atoms of one of the dichloro­methane mol­ecules is disordered over two sites in a 0.515 (3):0.485 (3) ratio. C—H⋯F hydrogen bonds stabilize the crystal packing. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007544/ /pubmed/21588157 http://dx.doi.org/10.1107/S1600536810025560 Text en © Engelbrecht et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate
title Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate
title_full Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate
title_fullStr Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate
title_full_unstemmed Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate
title_short Bis[N,N-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluoridophosphate) dichloro­methane disolvate
title_sort bis[n,n-bis­(diphenyl­phosphan­yl)pentyl­amine-κ(2) p,p′]platinum(ii) bis­(hexa­fluoridophosphate) dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007544/
https://www.ncbi.nlm.nih.gov/pubmed/21588157
http://dx.doi.org/10.1107/S1600536810025560
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AT visserhendrikg bisnnbisdiphenylphosphanylpentylaminek2ppplatinumiibishexafluoridophosphatedichloromethanedisolvate
AT roodtandreas bisnnbisdiphenylphosphanylpentylaminek2ppplatinumiibishexafluoridophosphatedichloromethanedisolvate

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