Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate

In the title compound, C(21)H(19)BrO(3), the cyclo­hexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 28.88 (10) and 71.94 (10)° with the bromo­benzene and phenyl rings, respectively. The dihedral angle be...

Descripción completa

Detalles Bibliográficos
Autores principales: Anuradha, N., Thiruvalluvar, A., Yuvaraj, C., Pandiarajan, K., Butcher, R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007547/
https://www.ncbi.nlm.nih.gov/pubmed/21588230
http://dx.doi.org/10.1107/S1600536810025353
_version_ 1782194384051109888
author Anuradha, N.
Thiruvalluvar, A.
Yuvaraj, C.
Pandiarajan, K.
Butcher, R. J.
author_facet Anuradha, N.
Thiruvalluvar, A.
Yuvaraj, C.
Pandiarajan, K.
Butcher, R. J.
author_sort Anuradha, N.
collection PubMed
description In the title compound, C(21)H(19)BrO(3), the cyclo­hexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 28.88 (10) and 71.94 (10)° with the bromo­benzene and phenyl rings, respectively. The dihedral angle between the latter two rings is 51.49 (15)°. Inter­molecular C—H⋯O hydrogen bonds are found in the crystal structure; a C—H⋯π inter­action is also present.
format Text
id pubmed-3007547
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30075472010-12-30 Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate Anuradha, N. Thiruvalluvar, A. Yuvaraj, C. Pandiarajan, K. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(19)BrO(3), the cyclo­hexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 28.88 (10) and 71.94 (10)° with the bromo­benzene and phenyl rings, respectively. The dihedral angle between the latter two rings is 51.49 (15)°. Inter­molecular C—H⋯O hydrogen bonds are found in the crystal structure; a C—H⋯π inter­action is also present. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007547/ /pubmed/21588230 http://dx.doi.org/10.1107/S1600536810025353 Text en © Anuradha et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anuradha, N.
Thiruvalluvar, A.
Yuvaraj, C.
Pandiarajan, K.
Butcher, R. J.
Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate
title Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate
title_full Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate
title_fullStr Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate
title_full_unstemmed Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate
title_short Ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate
title_sort ethyl 4-(4-bromo­phen­yl)-6-r-phenyl-2-oxocyclo­hex-3-ene-1-t-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007547/
https://www.ncbi.nlm.nih.gov/pubmed/21588230
http://dx.doi.org/10.1107/S1600536810025353
work_keys_str_mv AT anuradhan ethyl44bromophenyl6rphenyl2oxocyclohex3ene1tcarboxylate
AT thiruvalluvara ethyl44bromophenyl6rphenyl2oxocyclohex3ene1tcarboxylate
AT yuvarajc ethyl44bromophenyl6rphenyl2oxocyclohex3ene1tcarboxylate
AT pandiarajank ethyl44bromophenyl6rphenyl2oxocyclohex3ene1tcarboxylate
AT butcherrj ethyl44bromophenyl6rphenyl2oxocyclohex3ene1tcarboxylate

Ejemplares similares