Guanidinium phenyl­arsonate–guanidine–water (1/1/2)

In the structure of the title compound, CH(6)N(3) (+)·C(6)H(6)AsO(3) (−)·CH(5)N(3)·2H(2)O, the phenyl­arsonate anion participates in two R (2) (2)(8) cyclic hydrogen-bonding inter­actions, one with a guanidinium cation, the other with a guanidine mol­ecule. The anions are also bridged by the water m...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007548/
https://www.ncbi.nlm.nih.gov/pubmed/21588228
http://dx.doi.org/10.1107/S1600536810025043
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description In the structure of the title compound, CH(6)N(3) (+)·C(6)H(6)AsO(3) (−)·CH(5)N(3)·2H(2)O, the phenyl­arsonate anion participates in two R (2) (2)(8) cyclic hydrogen-bonding inter­actions, one with a guanidinium cation, the other with a guanidine mol­ecule. The anions are also bridged by the water mol­ecules, one of which completes a cyclic R (5) (3)(9) hydrogen-bonding association with the guanidinum cation, conjoint with one of the three R (2) (2)(8) associations about that ion, as well as forming an R (2) (1)(6) cyclic association with the guanidine mol­ecule. The result is a three-dimensional framework structure.
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spelling pubmed-30075482010-12-30 Guanidinium phenyl­arsonate–guanidine–water (1/1/2) Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, CH(6)N(3) (+)·C(6)H(6)AsO(3) (−)·CH(5)N(3)·2H(2)O, the phenyl­arsonate anion participates in two R (2) (2)(8) cyclic hydrogen-bonding inter­actions, one with a guanidinium cation, the other with a guanidine mol­ecule. The anions are also bridged by the water mol­ecules, one of which completes a cyclic R (5) (3)(9) hydrogen-bonding association with the guanidinum cation, conjoint with one of the three R (2) (2)(8) associations about that ion, as well as forming an R (2) (1)(6) cyclic association with the guanidine mol­ecule. The result is a three-dimensional framework structure. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007548/ /pubmed/21588228 http://dx.doi.org/10.1107/S1600536810025043 Text en © Smith and Wermuth 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
Guanidinium phenyl­arsonate–guanidine–water (1/1/2)
title Guanidinium phenyl­arsonate–guanidine–water (1/1/2)
title_full Guanidinium phenyl­arsonate–guanidine–water (1/1/2)
title_fullStr Guanidinium phenyl­arsonate–guanidine–water (1/1/2)
title_full_unstemmed Guanidinium phenyl­arsonate–guanidine–water (1/1/2)
title_short Guanidinium phenyl­arsonate–guanidine–water (1/1/2)
title_sort guanidinium phenyl­arsonate–guanidine–water (1/1/2)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007548/
https://www.ncbi.nlm.nih.gov/pubmed/21588228
http://dx.doi.org/10.1107/S1600536810025043
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