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{4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ(2) N′,O}dimethyltin(IV)
Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH(3))(2)(C(18)H(12)N(2)O(3))]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C(2)NO(2) donor set defines a coordi...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007549/ https://www.ncbi.nlm.nih.gov/pubmed/21588158 http://dx.doi.org/10.1107/S1600536810027078 |
| _version_ | 1782194384508289024 |
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| author | Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. Tiekink, Edward R. T. |
| author_facet | Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. Tiekink, Edward R. T. |
| author_sort | Affan, Md. Abu |
| collection | PubMed |
| description | Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH(3))(2)(C(18)H(12)N(2)O(3))]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C(2)NO(2) donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-pyramidal, with a small tendency towards the former. Zigzag chains running along the a axis mediated by O—H⋯N hydrogen bonding characterize the crystal packing. These are connected into layers in the ab plane by a combination of C—H⋯N and π–π [centroid–centroid distances = 3.658 (2) and 3.6740 (18) Å] interactions. The layers are connected along the c axis via C—H⋯O interactions. |
| format | Text |
| id | pubmed-3007549 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30075492010-12-30 {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ(2) N′,O}dimethyltin(IV) Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH(3))(2)(C(18)H(12)N(2)O(3))]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C(2)NO(2) donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-pyramidal, with a small tendency towards the former. Zigzag chains running along the a axis mediated by O—H⋯N hydrogen bonding characterize the crystal packing. These are connected into layers in the ab plane by a combination of C—H⋯N and π–π [centroid–centroid distances = 3.658 (2) and 3.6740 (18) Å] interactions. The layers are connected along the c axis via C—H⋯O interactions. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007549/ /pubmed/21588158 http://dx.doi.org/10.1107/S1600536810027078 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. Tiekink, Edward R. T. {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ(2) N′,O}dimethyltin(IV) |
| title | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ(2)
N′,O}dimethyltin(IV) |
| title_full | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ(2)
N′,O}dimethyltin(IV) |
| title_fullStr | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ(2)
N′,O}dimethyltin(IV) |
| title_full_unstemmed | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ(2)
N′,O}dimethyltin(IV) |
| title_short | {4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ(2)
N′,O}dimethyltin(IV) |
| title_sort | {4-hydroxy-n′-[(2-oxido-1-naphthyl-κo)methylidene]benzohydrazidato-κ(2)
n′,o}dimethyltin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007549/ https://www.ncbi.nlm.nih.gov/pubmed/21588158 http://dx.doi.org/10.1107/S1600536810027078 |
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