Ammonium hexa­fluorido­phosphate–18-crown-6 (1/1)

In the crystal structure of the title compound, NH(4) (+)·PF(6) (−)·C(12)H(24)O(6), the cation is situated in the 18-crown-6 ring, forming a supra­molecular rotator-stator-like structure held by N—H⋯O hydrogen bonds. The six O atoms of the crown ether lie approximately in a plane [mean deviation 0.2...

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Detalles Bibliográficos
Autores principales: Wu, De-Hong, Wu, Qi-Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007552/
https://www.ncbi.nlm.nih.gov/pubmed/21588421
http://dx.doi.org/10.1107/S160053681002920X
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author Wu, De-Hong
Wu, Qi-Qi
author_facet Wu, De-Hong
Wu, Qi-Qi
author_sort Wu, De-Hong
collection PubMed
description In the crystal structure of the title compound, NH(4) (+)·PF(6) (−)·C(12)H(24)O(6), the cation is situated in the 18-crown-6 ring, forming a supra­molecular rotator-stator-like structure held by N—H⋯O hydrogen bonds. The six O atoms of the crown ether lie approximately in a plane [mean deviation 0.2129 (3) Å]; the N atom is displaced by 0.864 (3)Å from the centroid of the 18-crown-6 ring. The slightly distorted tetra­hedral cations further inter­act with the slightly distorted octa­hedral anions via inter­molecular N—H⋯F hydrogen bonds.
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spelling pubmed-30075522010-12-30 Ammonium hexa­fluorido­phosphate–18-crown-6 (1/1) Wu, De-Hong Wu, Qi-Qi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, NH(4) (+)·PF(6) (−)·C(12)H(24)O(6), the cation is situated in the 18-crown-6 ring, forming a supra­molecular rotator-stator-like structure held by N—H⋯O hydrogen bonds. The six O atoms of the crown ether lie approximately in a plane [mean deviation 0.2129 (3) Å]; the N atom is displaced by 0.864 (3)Å from the centroid of the 18-crown-6 ring. The slightly distorted tetra­hedral cations further inter­act with the slightly distorted octa­hedral anions via inter­molecular N—H⋯F hydrogen bonds. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007552/ /pubmed/21588421 http://dx.doi.org/10.1107/S160053681002920X Text en © Wu and Wu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wu, De-Hong
Wu, Qi-Qi
Ammonium hexa­fluorido­phosphate–18-crown-6 (1/1)
title Ammonium hexa­fluorido­phosphate–18-crown-6 (1/1)
title_full Ammonium hexa­fluorido­phosphate–18-crown-6 (1/1)
title_fullStr Ammonium hexa­fluorido­phosphate–18-crown-6 (1/1)
title_full_unstemmed Ammonium hexa­fluorido­phosphate–18-crown-6 (1/1)
title_short Ammonium hexa­fluorido­phosphate–18-crown-6 (1/1)
title_sort ammonium hexa­fluorido­phosphate–18-crown-6 (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007552/
https://www.ncbi.nlm.nih.gov/pubmed/21588421
http://dx.doi.org/10.1107/S160053681002920X
work_keys_str_mv AT wudehong ammoniumhexafluoridophosphate18crown611
AT wuqiqi ammoniumhexafluoridophosphate18crown611

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