catena-Poly[[bis­(4-methyl­benzoato-κ(2) O:O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O]

In the title compound, [Pb(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)](n), the Pb(II) ion is coordinated by two 4-methyl­benzoate (PMB) and one nicotinamide (NA) ligands while symmetry-related NA ligands bridge adjacent Pb(II) ions, forming polymeric chains along the c axis. The carboxyl­ate groups in the two...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Çimen, Efdal, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007553/
https://www.ncbi.nlm.nih.gov/pubmed/21588183
http://dx.doi.org/10.1107/S1600536810028126
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Çimen, Efdal
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Çimen, Efdal
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the title compound, [Pb(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)](n), the Pb(II) ion is coordinated by two 4-methyl­benzoate (PMB) and one nicotinamide (NA) ligands while symmetry-related NA ligands bridge adjacent Pb(II) ions, forming polymeric chains along the c axis. The carboxyl­ate groups in the two PMB ions are twisted away from the attached benzene ring by 22.9 (2) and 4.6 (2)°. The two benzene rings of the PMB ions are oriented at a dihedral angle of 83.7 (1)°. In a polymeric chain, the NA ligands are linked to PMB ions through intra­molecular N—H⋯O hydrogen bonds. In the crystal structure, adjacent polymeric chains inter­act via N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane.
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spelling pubmed-30075532010-12-30 catena-Poly[[bis­(4-methyl­benzoato-κ(2) O:O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] Hökelek, Tuncer Dal, Hakan Tercan, Barış Çimen, Efdal Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)](n), the Pb(II) ion is coordinated by two 4-methyl­benzoate (PMB) and one nicotinamide (NA) ligands while symmetry-related NA ligands bridge adjacent Pb(II) ions, forming polymeric chains along the c axis. The carboxyl­ate groups in the two PMB ions are twisted away from the attached benzene ring by 22.9 (2) and 4.6 (2)°. The two benzene rings of the PMB ions are oriented at a dihedral angle of 83.7 (1)°. In a polymeric chain, the NA ligands are linked to PMB ions through intra­molecular N—H⋯O hydrogen bonds. In the crystal structure, adjacent polymeric chains inter­act via N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007553/ /pubmed/21588183 http://dx.doi.org/10.1107/S1600536810028126 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Çimen, Efdal
Necefoğlu, Hacali
catena-Poly[[bis­(4-methyl­benzoato-κ(2) O:O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O]
title catena-Poly[[bis­(4-methyl­benzoato-κ(2) O:O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O]
title_full catena-Poly[[bis­(4-methyl­benzoato-κ(2) O:O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O]
title_fullStr catena-Poly[[bis­(4-methyl­benzoato-κ(2) O:O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O]
title_full_unstemmed catena-Poly[[bis­(4-methyl­benzoato-κ(2) O:O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O]
title_short catena-Poly[[bis­(4-methyl­benzoato-κ(2) O:O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O]
title_sort catena-poly[[bis­(4-methyl­benzoato-κ(2) o:o′)lead(ii)]-μ-nicotinamide-κ(2) n (1):o]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007553/
https://www.ncbi.nlm.nih.gov/pubmed/21588183
http://dx.doi.org/10.1107/S1600536810028126
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