Cargando…
(Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3) O,N′,O′)(methoxo-κO)oxidovanadate(V)
The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O′ atoms spanning three basal positions of the square-based-pyrimidally V(V) atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent mol...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007558/ https://www.ncbi.nlm.nih.gov/pubmed/21588096 http://dx.doi.org/10.1107/S1600536810028898 |
| _version_ | 1782194386644238336 |
|---|---|
| author | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_facet | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_sort | Wong, Hon Wee |
| collection | PubMed |
| description | The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O′ atoms spanning three basal positions of the square-based-pyrimidally V(V) atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent molecule, and the oxido ligand occupies the apical position. The hydroxy H atom forms an intramolecular O—H⋯N hydrogen bond with an N-atom acceptor site. |
| format | Text |
| id | pubmed-3007558 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30075582010-12-30 (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3) O,N′,O′)(methoxo-κO)oxidovanadate(V) Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O′ atoms spanning three basal positions of the square-based-pyrimidally V(V) atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent molecule, and the oxido ligand occupies the apical position. The hydroxy H atom forms an intramolecular O—H⋯N hydrogen bond with an N-atom acceptor site. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007558/ /pubmed/21588096 http://dx.doi.org/10.1107/S1600536810028898 Text en © Wong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3) O,N′,O′)(methoxo-κO)oxidovanadate(V) |
| title | (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3)
O,N′,O′)(methoxo-κO)oxidovanadate(V) |
| title_full | (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3)
O,N′,O′)(methoxo-κO)oxidovanadate(V) |
| title_fullStr | (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3)
O,N′,O′)(methoxo-κO)oxidovanadate(V) |
| title_full_unstemmed | (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3)
O,N′,O′)(methoxo-κO)oxidovanadate(V) |
| title_short | (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3)
O,N′,O′)(methoxo-κO)oxidovanadate(V) |
| title_sort | (acetylacetone 3-hydroxy-2-naphthoylhydrazonato-κ(3)
o,n′,o′)(methoxo-κo)oxidovanadate(v) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007558/ https://www.ncbi.nlm.nih.gov/pubmed/21588096 http://dx.doi.org/10.1107/S1600536810028898 |
| work_keys_str_mv | AT wonghonwee acetylacetone3hydroxy2naphthoylhydrazonatok3onomethoxokooxidovanadatev AT lokongmun acetylacetone3hydroxy2naphthoylhydrazonatok3onomethoxokooxidovanadatev AT ngseikweng acetylacetone3hydroxy2naphthoylhydrazonatok3onomethoxokooxidovanadatev |