5-Bromo-1H-thieno[2,3-d]imidazole

The crystal structure of the title compound, C(5)H(3)BrN(2)S, shows that bromination of 1H-thieno[2,3-d]imidazole with N-bromo­succinimide in acetonitrile occurs at position 5 of the bicyclic system. The mol­ecule is almost planar, with a mean deviation of 0.015 Å from the least-squares plane throug...

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Detalles Bibliográficos
Autores principales: Wang, Fen, Ninkovic, Sacha, Collins, Michael, Moore, Curtis, Rheingold, Arnold L., Yanovsky, Alex
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007560/
https://www.ncbi.nlm.nih.gov/pubmed/21588332
http://dx.doi.org/10.1107/S1600536810027224
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author Wang, Fen
Ninkovic, Sacha
Collins, Michael
Moore, Curtis
Rheingold, Arnold L.
Yanovsky, Alex
author_facet Wang, Fen
Ninkovic, Sacha
Collins, Michael
Moore, Curtis
Rheingold, Arnold L.
Yanovsky, Alex
author_sort Wang, Fen
collection PubMed
description The crystal structure of the title compound, C(5)H(3)BrN(2)S, shows that bromination of 1H-thieno[2,3-d]imidazole with N-bromo­succinimide in acetonitrile occurs at position 5 of the bicyclic system. The mol­ecule is almost planar, with a mean deviation of 0.015 Å from the least-squares plane through all the non-H atoms. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into infinite C(4) chains running along [101].
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spelling pubmed-30075602010-12-30 5-Bromo-1H-thieno[2,3-d]imidazole Wang, Fen Ninkovic, Sacha Collins, Michael Moore, Curtis Rheingold, Arnold L. Yanovsky, Alex Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(5)H(3)BrN(2)S, shows that bromination of 1H-thieno[2,3-d]imidazole with N-bromo­succinimide in acetonitrile occurs at position 5 of the bicyclic system. The mol­ecule is almost planar, with a mean deviation of 0.015 Å from the least-squares plane through all the non-H atoms. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into infinite C(4) chains running along [101]. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007560/ /pubmed/21588332 http://dx.doi.org/10.1107/S1600536810027224 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Fen
Ninkovic, Sacha
Collins, Michael
Moore, Curtis
Rheingold, Arnold L.
Yanovsky, Alex
5-Bromo-1H-thieno[2,3-d]imidazole
title 5-Bromo-1H-thieno[2,3-d]imidazole
title_full 5-Bromo-1H-thieno[2,3-d]imidazole
title_fullStr 5-Bromo-1H-thieno[2,3-d]imidazole
title_full_unstemmed 5-Bromo-1H-thieno[2,3-d]imidazole
title_short 5-Bromo-1H-thieno[2,3-d]imidazole
title_sort 5-bromo-1h-thieno[2,3-d]imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007560/
https://www.ncbi.nlm.nih.gov/pubmed/21588332
http://dx.doi.org/10.1107/S1600536810027224
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AT ninkovicsacha 5bromo1hthieno23dimidazole
AT collinsmichael 5bromo1hthieno23dimidazole
AT moorecurtis 5bromo1hthieno23dimidazole
AT rheingoldarnoldl 5bromo1hthieno23dimidazole
AT yanovskyalex 5bromo1hthieno23dimidazole

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