N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate

In the asymmetric unit of the title compound, C(19)H(27)ClN(4)O·0.5C(2)H(6)O·1.5H(2)O, there are two mol­ecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH–N=CH– chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)° imidazolyl ring at the other end, th...

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Autores principales: Al-Tamimi, Abdul-Malek S., Bari, Ahmed, Al-Omar, Mohamed A., El-Emam, Ali A., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007568/
https://www.ncbi.nlm.nih.gov/pubmed/21588420
http://dx.doi.org/10.1107/S1600536810029260
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author Al-Tamimi, Abdul-Malek S.
Bari, Ahmed
Al-Omar, Mohamed A.
El-Emam, Ali A.
Ng, Seik Weng
author_facet Al-Tamimi, Abdul-Malek S.
Bari, Ahmed
Al-Omar, Mohamed A.
El-Emam, Ali A.
Ng, Seik Weng
author_sort Al-Tamimi, Abdul-Malek S.
collection PubMed
description In the asymmetric unit of the title compound, C(19)H(27)ClN(4)O·0.5C(2)H(6)O·1.5H(2)O, there are two mol­ecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH–N=CH– chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)° imidazolyl ring at the other end, three mol­ecules of water and one mol­ecule of ethanol. In both independent mol­ecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water mol­ecules; these are linked to other acceptor atoms, generating a layer structure. O—H⋯O and O—H⋯N inter­actions involving the water mol­ecules also occur.
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spelling pubmed-30075682010-12-30 N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate Al-Tamimi, Abdul-Malek S. Bari, Ahmed Al-Omar, Mohamed A. El-Emam, Ali A. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, C(19)H(27)ClN(4)O·0.5C(2)H(6)O·1.5H(2)O, there are two mol­ecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH–N=CH– chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)° imidazolyl ring at the other end, three mol­ecules of water and one mol­ecule of ethanol. In both independent mol­ecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water mol­ecules; these are linked to other acceptor atoms, generating a layer structure. O—H⋯O and O—H⋯N inter­actions involving the water mol­ecules also occur. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007568/ /pubmed/21588420 http://dx.doi.org/10.1107/S1600536810029260 Text en © Al-Tamimi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Tamimi, Abdul-Malek S.
Bari, Ahmed
Al-Omar, Mohamed A.
El-Emam, Ali A.
Ng, Seik Weng
N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate
title N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate
title_full N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate
title_fullStr N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate
title_full_unstemmed N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate
title_short N′-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate
title_sort n′-[(2-n-butyl-4-chloro-1h-imidazol-5-yl)­methyl­idene]adamantane-1-carbo­hydrazide sesquihydrate ethanol hemi­solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007568/
https://www.ncbi.nlm.nih.gov/pubmed/21588420
http://dx.doi.org/10.1107/S1600536810029260
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