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Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II)
In the title compound, [Hg(C(14)H(13)N(4)O(3))Cl], the Hg(II) atom is four-coordinated by one O atom and two N atoms from a tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligand and one terminal chloride ion in a distorted square-planar geometry. In the crystal structure, the mononuc...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007569/ https://www.ncbi.nlm.nih.gov/pubmed/21588199 http://dx.doi.org/10.1107/S1600536810027819 |
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author | Melardi, Mohammad Reza Roohi, Zeynab Heidari, Nazanin Rofouei, Mohammad Kazem |
author_facet | Melardi, Mohammad Reza Roohi, Zeynab Heidari, Nazanin Rofouei, Mohammad Kazem |
author_sort | Melardi, Mohammad Reza |
collection | PubMed |
description | In the title compound, [Hg(C(14)H(13)N(4)O(3))Cl], the Hg(II) atom is four-coordinated by one O atom and two N atoms from a tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligand and one terminal chloride ion in a distorted square-planar geometry. In the crystal structure, the mononuclear complexes are linked into pairs through C—H⋯O and C—H⋯Cl hydrogen bonds as well as π–π and C—H⋯π stacking interactions. In addition, weak Hg–μ(6)-arene π-interactions [mean distance of 3.667 (2) Å] are present between these dimers. The π–π stacking interactions are between aromatic rings with a centroid–centroid distance of 3.884 (2) Å. Moreover, edge-to-face interactions are present between ethoxy CH groups and aromatic rings with H⋯π distances of 2.81 Å. |
format | Text |
id | pubmed-3007569 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30075692010-12-30 Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) Melardi, Mohammad Reza Roohi, Zeynab Heidari, Nazanin Rofouei, Mohammad Kazem Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(C(14)H(13)N(4)O(3))Cl], the Hg(II) atom is four-coordinated by one O atom and two N atoms from a tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligand and one terminal chloride ion in a distorted square-planar geometry. In the crystal structure, the mononuclear complexes are linked into pairs through C—H⋯O and C—H⋯Cl hydrogen bonds as well as π–π and C—H⋯π stacking interactions. In addition, weak Hg–μ(6)-arene π-interactions [mean distance of 3.667 (2) Å] are present between these dimers. The π–π stacking interactions are between aromatic rings with a centroid–centroid distance of 3.884 (2) Å. Moreover, edge-to-face interactions are present between ethoxy CH groups and aromatic rings with H⋯π distances of 2.81 Å. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007569/ /pubmed/21588199 http://dx.doi.org/10.1107/S1600536810027819 Text en © Melardi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Melardi, Mohammad Reza Roohi, Zeynab Heidari, Nazanin Rofouei, Mohammad Kazem Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
title | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
title_full | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
title_fullStr | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
title_full_unstemmed | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
title_short | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
title_sort | chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007569/ https://www.ncbi.nlm.nih.gov/pubmed/21588199 http://dx.doi.org/10.1107/S1600536810027819 |
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