(18-Crown-6)(trifluoro­methane­sulfonato)­sodium

The title compound, [Na(CF(3)O(3)S)(C(12)H(24)O(6))], features a sodium cation that is coordinated by eight O atoms in an irregular hexa­gonal bipyramidal environment. The equatorial positions are occupied by the six O atoms of an 18-crown-6 ether ring. In the axial positions, there is one O atom of...

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Detalles Bibliográficos
Autores principales: Phan, Hien Ngoc, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007570/
https://www.ncbi.nlm.nih.gov/pubmed/21588137
http://dx.doi.org/10.1107/S1600536810025961
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author Phan, Hien Ngoc
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Phan, Hien Ngoc
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Phan, Hien Ngoc
collection PubMed
description The title compound, [Na(CF(3)O(3)S)(C(12)H(24)O(6))], features a sodium cation that is coordinated by eight O atoms in an irregular hexa­gonal bipyramidal environment. The equatorial positions are occupied by the six O atoms of an 18-crown-6 ether ring. In the axial positions, there is one O atom of a trifluoro­methane­sulfonate anion and an ether O atom of a symmetry-equivalent crown ether ring. In this way, centrosymmetric dimers are formed.
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spelling pubmed-30075702010-12-30 (18-Crown-6)(trifluoro­methane­sulfonato)­sodium Phan, Hien Ngoc Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Na(CF(3)O(3)S)(C(12)H(24)O(6))], features a sodium cation that is coordinated by eight O atoms in an irregular hexa­gonal bipyramidal environment. The equatorial positions are occupied by the six O atoms of an 18-crown-6 ether ring. In the axial positions, there is one O atom of a trifluoro­methane­sulfonate anion and an ether O atom of a symmetry-equivalent crown ether ring. In this way, centrosymmetric dimers are formed. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007570/ /pubmed/21588137 http://dx.doi.org/10.1107/S1600536810025961 Text en © Phan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Phan, Hien Ngoc
Lerner, Hans-Wolfram
Bolte, Michael
(18-Crown-6)(trifluoro­methane­sulfonato)­sodium
title (18-Crown-6)(trifluoro­methane­sulfonato)­sodium
title_full (18-Crown-6)(trifluoro­methane­sulfonato)­sodium
title_fullStr (18-Crown-6)(trifluoro­methane­sulfonato)­sodium
title_full_unstemmed (18-Crown-6)(trifluoro­methane­sulfonato)­sodium
title_short (18-Crown-6)(trifluoro­methane­sulfonato)­sodium
title_sort (18-crown-6)(trifluoro­methane­sulfonato)­sodium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007570/
https://www.ncbi.nlm.nih.gov/pubmed/21588137
http://dx.doi.org/10.1107/S1600536810025961
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AT lernerhanswolfram 18crown6trifluoromethanesulfonatosodium
AT boltemichael 18crown6trifluoromethanesulfonatosodium

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