N-Methyl-2-thio­cytisine

The rings of the three-ring cytisine system in the title compound [systematic name: (1R,5S)-1,2,3,4,5,6-hexa­hydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazo­cine-8-thione], C(12)H(16)N(2)S, have planar [maximum deviation 0.0170 (7) Å], half-chair and chair conformations. In the crystal structure, relat...

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Detalles Bibliográficos
Autores principales: Owczarzak, Anita M., Przybył, Anna K., Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007573/
https://www.ncbi.nlm.nih.gov/pubmed/21588268
http://dx.doi.org/10.1107/S1600536810025870
Descripción
Sumario:The rings of the three-ring cytisine system in the title compound [systematic name: (1R,5S)-1,2,3,4,5,6-hexa­hydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazo­cine-8-thione], C(12)H(16)N(2)S, have planar [maximum deviation 0.0170 (7) Å], half-chair and chair conformations. In the crystal structure, relatively short and directional C—H⋯π inter­actions and weaker secondary C—H⋯S contacts join the mol­ecules into helical chains along the [001] direction.

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