N-Methyl-2-thio­cytisine

The rings of the three-ring cytisine system in the title compound [systematic name: (1R,5S)-1,2,3,4,5,6-hexa­hydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazo­cine-8-thione], C(12)H(16)N(2)S, have planar [maximum deviation 0.0170 (7) Å], half-chair and chair conformations. In the crystal structure, relat...

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Detalles Bibliográficos
Autores principales: Owczarzak, Anita M., Przybył, Anna K., Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007573/
https://www.ncbi.nlm.nih.gov/pubmed/21588268
http://dx.doi.org/10.1107/S1600536810025870
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author Owczarzak, Anita M.
Przybył, Anna K.
Kubicki, Maciej
author_facet Owczarzak, Anita M.
Przybył, Anna K.
Kubicki, Maciej
author_sort Owczarzak, Anita M.
collection PubMed
description The rings of the three-ring cytisine system in the title compound [systematic name: (1R,5S)-1,2,3,4,5,6-hexa­hydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazo­cine-8-thione], C(12)H(16)N(2)S, have planar [maximum deviation 0.0170 (7) Å], half-chair and chair conformations. In the crystal structure, relatively short and directional C—H⋯π inter­actions and weaker secondary C—H⋯S contacts join the mol­ecules into helical chains along the [001] direction.
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spelling pubmed-30075732010-12-30 N-Methyl-2-thio­cytisine Owczarzak, Anita M. Przybył, Anna K. Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Organic Papers The rings of the three-ring cytisine system in the title compound [systematic name: (1R,5S)-1,2,3,4,5,6-hexa­hydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazo­cine-8-thione], C(12)H(16)N(2)S, have planar [maximum deviation 0.0170 (7) Å], half-chair and chair conformations. In the crystal structure, relatively short and directional C—H⋯π inter­actions and weaker secondary C—H⋯S contacts join the mol­ecules into helical chains along the [001] direction. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007573/ /pubmed/21588268 http://dx.doi.org/10.1107/S1600536810025870 Text en © Owczarzak et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Owczarzak, Anita M.
Przybył, Anna K.
Kubicki, Maciej
N-Methyl-2-thio­cytisine
title N-Methyl-2-thio­cytisine
title_full N-Methyl-2-thio­cytisine
title_fullStr N-Methyl-2-thio­cytisine
title_full_unstemmed N-Methyl-2-thio­cytisine
title_short N-Methyl-2-thio­cytisine
title_sort n-methyl-2-thio­cytisine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007573/
https://www.ncbi.nlm.nih.gov/pubmed/21588268
http://dx.doi.org/10.1107/S1600536810025870
work_keys_str_mv AT owczarzakanitam nmethyl2thiocytisine
AT przybyłannak nmethyl2thiocytisine
AT kubickimaciej nmethyl2thiocytisine

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