Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate

In the title compound, [Ni(C(19)H(13)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Ni(II) ion is coordinated by two tridentate 2,6-bis­(1H-benzimidazol-2-yl)pyridine ligands in a distorted octa­hedral geometry. In the crystal structure, the picrate anions and solvent dimethyl­formamide (DMF) mol­e...

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Detalles Bibliográficos
Autores principales: Huang, Xingcai, Kou, Fan, Qi, Baoliang, Meng, Xuan, Wu, Huilu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007574/
https://www.ncbi.nlm.nih.gov/pubmed/21588192
http://dx.doi.org/10.1107/S160053681002773X
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author Huang, Xingcai
Kou, Fan
Qi, Baoliang
Meng, Xuan
Wu, Huilu
author_facet Huang, Xingcai
Kou, Fan
Qi, Baoliang
Meng, Xuan
Wu, Huilu
author_sort Huang, Xingcai
collection PubMed
description In the title compound, [Ni(C(19)H(13)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Ni(II) ion is coordinated by two tridentate 2,6-bis­(1H-benzimidazol-2-yl)pyridine ligands in a distorted octa­hedral geometry. In the crystal structure, the picrate anions and solvent dimethyl­formamide (DMF) mol­ecules are connected to the cation via inter­molecular N—H⋯O hydrogen bonds. Further stabilization is provided by weak inter­molecular C—H⋯O hydrogen bonds. One of the DMF moleclues is disordered over two sites with refined occupancies of 0.737 (3) and 0.263 (3).
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spelling pubmed-30075742010-12-30 Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate Huang, Xingcai Kou, Fan Qi, Baoliang Meng, Xuan Wu, Huilu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(19)H(13)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Ni(II) ion is coordinated by two tridentate 2,6-bis­(1H-benzimidazol-2-yl)pyridine ligands in a distorted octa­hedral geometry. In the crystal structure, the picrate anions and solvent dimethyl­formamide (DMF) mol­ecules are connected to the cation via inter­molecular N—H⋯O hydrogen bonds. Further stabilization is provided by weak inter­molecular C—H⋯O hydrogen bonds. One of the DMF moleclues is disordered over two sites with refined occupancies of 0.737 (3) and 0.263 (3). International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007574/ /pubmed/21588192 http://dx.doi.org/10.1107/S160053681002773X Text en © Huang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Xingcai
Kou, Fan
Qi, Baoliang
Meng, Xuan
Wu, Huilu
Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate
title Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate
title_full Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate
title_fullStr Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate
title_full_unstemmed Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate
title_short Bis[2,6-bis­(1H-benzimidazol-2-yl)pyridine]­nickel(II) dipicrate dimethyl­formamide disolvate
title_sort bis[2,6-bis­(1h-benzimidazol-2-yl)pyridine]­nickel(ii) dipicrate dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007574/
https://www.ncbi.nlm.nih.gov/pubmed/21588192
http://dx.doi.org/10.1107/S160053681002773X
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