Dichloridobis(1,3-phenyl­propane-1,3-dionato-κ(2) O,O′)tin(IV) toluene hemisolvate

The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]·0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are...

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Detalles Bibliográficos
Autores principales: Thy, Chun Keng, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007579/
https://www.ncbi.nlm.nih.gov/pubmed/21588212
http://dx.doi.org/10.1107/S1600536810028084
Descripción
Sumario:The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]·0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are aligned at an angle of 59.6 (1)°. The Cl atoms occupy cis positions in the octa­hedral SnCl(2)O(4) coordination environment. The solvent mol­ecule is disordered about a center of inversion.

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