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Dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2) O,O′)tin(IV) toluene hemisolvate
The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]·0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007579/ https://www.ncbi.nlm.nih.gov/pubmed/21588212 http://dx.doi.org/10.1107/S1600536810028084 |
| _version_ | 1782194391591419904 |
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| author | Thy, Chun Keng Lo, Kong Mun Ng, Seik Weng |
| author_facet | Thy, Chun Keng Lo, Kong Mun Ng, Seik Weng |
| author_sort | Thy, Chun Keng |
| collection | PubMed |
| description | The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]·0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are aligned at an angle of 59.6 (1)°. The Cl atoms occupy cis positions in the octahedral SnCl(2)O(4) coordination environment. The solvent molecule is disordered about a center of inversion. |
| format | Text |
| id | pubmed-3007579 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30075792010-12-30 Dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2) O,O′)tin(IV) toluene hemisolvate Thy, Chun Keng Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]·0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are aligned at an angle of 59.6 (1)°. The Cl atoms occupy cis positions in the octahedral SnCl(2)O(4) coordination environment. The solvent molecule is disordered about a center of inversion. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007579/ /pubmed/21588212 http://dx.doi.org/10.1107/S1600536810028084 Text en © Thy et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Thy, Chun Keng Lo, Kong Mun Ng, Seik Weng Dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2) O,O′)tin(IV) toluene hemisolvate |
| title | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2)
O,O′)tin(IV) toluene hemisolvate |
| title_full | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2)
O,O′)tin(IV) toluene hemisolvate |
| title_fullStr | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2)
O,O′)tin(IV) toluene hemisolvate |
| title_full_unstemmed | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2)
O,O′)tin(IV) toluene hemisolvate |
| title_short | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2)
O,O′)tin(IV) toluene hemisolvate |
| title_sort | dichloridobis(1,3-phenylpropane-1,3-dionato-κ(2)
o,o′)tin(iv) toluene hemisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007579/ https://www.ncbi.nlm.nih.gov/pubmed/21588212 http://dx.doi.org/10.1107/S1600536810028084 |
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