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catena-poly[[[(2,2′-bipyridine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-cyanido-2κC-tris­(methanol-1κO)(nitrato-1κ(2) O,O′)iron(II)yttrium(III)]-di-μ-cyanido-1:2′κ(2) N:C;2:1′κ(2) C:N] methanol solvate hemihydrate]

The title complex, {[Fe(II)Y(III)(CN)(4)(NO(3))(C(10)H(8)N(2))(CH(3)OH)(3)]·CH(3)OH·0.5H(2)O}(n), is built up of ladder-like chains oriented along the c axis. Each ladder consists of two strands based on alternating Fe(II) and Y(III) ions connected by cyanide bridges. Two such parallel chains are co...

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Autores principales: Xu, Yan, Shu, He-Qing, Shen, Xiao-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007586/
https://www.ncbi.nlm.nih.gov/pubmed/21588108
http://dx.doi.org/10.1107/S1600536810029843
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author Xu, Yan
Shu, He-Qing
Shen, Xiao-Ping
author_facet Xu, Yan
Shu, He-Qing
Shen, Xiao-Ping
author_sort Xu, Yan
collection PubMed
description The title complex, {[Fe(II)Y(III)(CN)(4)(NO(3))(C(10)H(8)N(2))(CH(3)OH)(3)]·CH(3)OH·0.5H(2)O}(n), is built up of ladder-like chains oriented along the c axis. Each ladder consists of two strands based on alternating Fe(II) and Y(III) ions connected by cyanide bridges. Two such parallel chains are connected by additional cyanide anions (the ‘rungs’ of the ladder), which likewise connect Fe(II) and Y(III) ions, such that each [Fe(bipy)(CN)(4)](2−) (bipy is 2,2′-bipyridine) unit coordinates with three Y(III) ions and each Y(III) ion connects with three different [Fe(bipy)(CN)(4)](2−) units. The Fe(II) atom is six-coordinated in a distorted octa­hedral geometry and the Y(III) atom cation is eight-coordinated in a distorted dodeca­hedral environment. The uncoordinated methanol solvent mol­ecules are involved in hydrogen-bonding inter­actions with the one terminal cyanide group and a coordinated methanol mol­ecule from another [Y(III)(NO(3))(CH(3)OH)(3)](2+) unit. Adjacent ladder-like chains are also held together by hydrogen bonds between the terminal cyanide ligands of the [Fe(CN)(4)(bipy)](2−) units in one chain and the OH donors of CH(3)OH ligands from [Y(III)(NO(3))(CH(3)OH)(3)] units in neighboring chains. The water molecule exhibits half-occupation.
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spelling pubmed-30075862010-12-30 catena-poly[[[(2,2′-bipyridine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-cyanido-2κC-tris­(methanol-1κO)(nitrato-1κ(2) O,O′)iron(II)yttrium(III)]-di-μ-cyanido-1:2′κ(2) N:C;2:1′κ(2) C:N] methanol solvate hemihydrate] Xu, Yan Shu, He-Qing Shen, Xiao-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, {[Fe(II)Y(III)(CN)(4)(NO(3))(C(10)H(8)N(2))(CH(3)OH)(3)]·CH(3)OH·0.5H(2)O}(n), is built up of ladder-like chains oriented along the c axis. Each ladder consists of two strands based on alternating Fe(II) and Y(III) ions connected by cyanide bridges. Two such parallel chains are connected by additional cyanide anions (the ‘rungs’ of the ladder), which likewise connect Fe(II) and Y(III) ions, such that each [Fe(bipy)(CN)(4)](2−) (bipy is 2,2′-bipyridine) unit coordinates with three Y(III) ions and each Y(III) ion connects with three different [Fe(bipy)(CN)(4)](2−) units. The Fe(II) atom is six-coordinated in a distorted octa­hedral geometry and the Y(III) atom cation is eight-coordinated in a distorted dodeca­hedral environment. The uncoordinated methanol solvent mol­ecules are involved in hydrogen-bonding inter­actions with the one terminal cyanide group and a coordinated methanol mol­ecule from another [Y(III)(NO(3))(CH(3)OH)(3)](2+) unit. Adjacent ladder-like chains are also held together by hydrogen bonds between the terminal cyanide ligands of the [Fe(CN)(4)(bipy)](2−) units in one chain and the OH donors of CH(3)OH ligands from [Y(III)(NO(3))(CH(3)OH)(3)] units in neighboring chains. The water molecule exhibits half-occupation. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007586/ /pubmed/21588108 http://dx.doi.org/10.1107/S1600536810029843 Text en © Xu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Yan
Shu, He-Qing
Shen, Xiao-Ping
catena-poly[[[(2,2′-bipyridine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-cyanido-2κC-tris­(methanol-1κO)(nitrato-1κ(2) O,O′)iron(II)yttrium(III)]-di-μ-cyanido-1:2′κ(2) N:C;2:1′κ(2) C:N] methanol solvate hemihydrate]
title catena-poly[[[(2,2′-bipyridine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-cyanido-2κC-tris­(methanol-1κO)(nitrato-1κ(2) O,O′)iron(II)yttrium(III)]-di-μ-cyanido-1:2′κ(2) N:C;2:1′κ(2) C:N] methanol solvate hemihydrate]
title_full catena-poly[[[(2,2′-bipyridine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-cyanido-2κC-tris­(methanol-1κO)(nitrato-1κ(2) O,O′)iron(II)yttrium(III)]-di-μ-cyanido-1:2′κ(2) N:C;2:1′κ(2) C:N] methanol solvate hemihydrate]
title_fullStr catena-poly[[[(2,2′-bipyridine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-cyanido-2κC-tris­(methanol-1κO)(nitrato-1κ(2) O,O′)iron(II)yttrium(III)]-di-μ-cyanido-1:2′κ(2) N:C;2:1′κ(2) C:N] methanol solvate hemihydrate]
title_full_unstemmed catena-poly[[[(2,2′-bipyridine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-cyanido-2κC-tris­(methanol-1κO)(nitrato-1κ(2) O,O′)iron(II)yttrium(III)]-di-μ-cyanido-1:2′κ(2) N:C;2:1′κ(2) C:N] methanol solvate hemihydrate]
title_short catena-poly[[[(2,2′-bipyridine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-cyanido-2κC-tris­(methanol-1κO)(nitrato-1κ(2) O,O′)iron(II)yttrium(III)]-di-μ-cyanido-1:2′κ(2) N:C;2:1′κ(2) C:N] methanol solvate hemihydrate]
title_sort catena-poly[[[(2,2′-bipyridine-2κ(2) n,n′)-μ-cyanido-1:2κ(2) n:c-cyanido-2κc-tris­(methanol-1κo)(nitrato-1κ(2) o,o′)iron(ii)yttrium(iii)]-di-μ-cyanido-1:2′κ(2) n:c;2:1′κ(2) c:n] methanol solvate hemihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007586/
https://www.ncbi.nlm.nih.gov/pubmed/21588108
http://dx.doi.org/10.1107/S1600536810029843
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