Bis(μ-quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[chloridomethyl­phenyl­tin(IV)]

The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa­hedral coordination [C–Sn–C = 157.83 (8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-relat...

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Detalles Bibliográficos
Autores principales: Vafaee, Maryam, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007587/
https://www.ncbi.nlm.nih.gov/pubmed/21588189
http://dx.doi.org/10.1107/S1600536810027765
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author Vafaee, Maryam
Amini, Mostafa M.
Ng, Seik Weng
author_facet Vafaee, Maryam
Amini, Mostafa M.
Ng, Seik Weng
author_sort Vafaee, Maryam
collection PubMed
description The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa­hedral coordination [C–Sn–C = 157.83 (8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter­molecular C—H⋯Cl hydrogen bonding links the mol­ecules, forming supra­molecular chains running along [100].
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spelling pubmed-30075872010-12-30 Bis(μ-quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[chloridomethyl­phenyl­tin(IV)] Vafaee, Maryam Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa­hedral coordination [C–Sn–C = 157.83 (8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter­molecular C—H⋯Cl hydrogen bonding links the mol­ecules, forming supra­molecular chains running along [100]. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007587/ /pubmed/21588189 http://dx.doi.org/10.1107/S1600536810027765 Text en © Vafaee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vafaee, Maryam
Amini, Mostafa M.
Ng, Seik Weng
Bis(μ-quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[chloridomethyl­phenyl­tin(IV)]
title Bis(μ-quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[chloridomethyl­phenyl­tin(IV)]
title_full Bis(μ-quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[chloridomethyl­phenyl­tin(IV)]
title_fullStr Bis(μ-quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[chloridomethyl­phenyl­tin(IV)]
title_full_unstemmed Bis(μ-quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[chloridomethyl­phenyl­tin(IV)]
title_short Bis(μ-quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[chloridomethyl­phenyl­tin(IV)]
title_sort bis(μ-quinolin-8-olato)-κ(3) n,o:o;κ(3) o:n,o-bis­[chloridomethyl­phenyl­tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007587/
https://www.ncbi.nlm.nih.gov/pubmed/21588189
http://dx.doi.org/10.1107/S1600536810027765
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