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Nicotinamide-independent asymmetric bioreduction of C[bond, double bond]C-bonds via disproportionation of enones catalyzed by enoate reductases
The asymmetric bioreduction of activated C[bond, double bond]C-bonds catalyzed by a single flavoprotein was achieved via direct hydrogen transfer from a sacrificial 2-enone or 1,4-dione as hydrogen donor without requirement of a nicotinamide cofactor. Due to its simplicity, this system has clear adv...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Pergamon Press
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007678/ https://www.ncbi.nlm.nih.gov/pubmed/21270958 http://dx.doi.org/10.1016/j.tet.2009.11.065 |