trans-Bis(ethyl­enediamine)­bis­{2-[N-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(II)

The title mononuclear Ni(II) complex, [Ni(C(11)H(11)N(2)O(5))(2)(C(2)H(8)N(2))(2)], is built up by inversion symmetry associated with the central Ni atom. The ethyl­enediamine ligands are non-planar. The r.m.s. deviation from the mean plane of the five-membered Ni–ethyl­amine chelate ring plane is 0...

Descripción completa

Detalles Bibliográficos
Autor principal: Yu, Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007825/
https://www.ncbi.nlm.nih.gov/pubmed/21588538
http://dx.doi.org/10.1107/S1600536810032848
_version_ 1782194436617273344
author Yu, Jun
author_facet Yu, Jun
author_sort Yu, Jun
collection PubMed
description The title mononuclear Ni(II) complex, [Ni(C(11)H(11)N(2)O(5))(2)(C(2)H(8)N(2))(2)], is built up by inversion symmetry associated with the central Ni atom. The ethyl­enediamine ligands are non-planar. The r.m.s. deviation from the mean plane of the five-membered Ni–ethyl­amine chelate ring plane is 0.1945 Å. In the crystal structure, complex mol­ecules are linked to each other via N—H⋯O and O—-H⋯O hydrogen bonding through translation symmetry along the b and c axes, resulting in an extended supra­molecular network.
format Text
id pubmed-3007825
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30078252010-12-30 trans-Bis(ethyl­enediamine)­bis­{2-[N-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(II) Yu, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear Ni(II) complex, [Ni(C(11)H(11)N(2)O(5))(2)(C(2)H(8)N(2))(2)], is built up by inversion symmetry associated with the central Ni atom. The ethyl­enediamine ligands are non-planar. The r.m.s. deviation from the mean plane of the five-membered Ni–ethyl­amine chelate ring plane is 0.1945 Å. In the crystal structure, complex mol­ecules are linked to each other via N—H⋯O and O—-H⋯O hydrogen bonding through translation symmetry along the b and c axes, resulting in an extended supra­molecular network. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007825/ /pubmed/21588538 http://dx.doi.org/10.1107/S1600536810032848 Text en © Jun Yu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Jun
trans-Bis(ethyl­enediamine)­bis­{2-[N-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(II)
title trans-Bis(ethyl­enediamine)­bis­{2-[N-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(II)
title_full trans-Bis(ethyl­enediamine)­bis­{2-[N-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(II)
title_fullStr trans-Bis(ethyl­enediamine)­bis­{2-[N-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(II)
title_full_unstemmed trans-Bis(ethyl­enediamine)­bis­{2-[N-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(II)
title_short trans-Bis(ethyl­enediamine)­bis­{2-[N-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(II)
title_sort trans-bis(ethyl­enediamine)­bis­{2-[n-(2-hy­droxy­eth­yl)oxamoyl­amino]­benzoato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007825/
https://www.ncbi.nlm.nih.gov/pubmed/21588538
http://dx.doi.org/10.1107/S1600536810032848
work_keys_str_mv AT yujun transbisethylenediaminebis2n2hydroxyethyloxamoylaminobenzoatonickelii

Ejemplares similares