Di-μ-sulfato-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate

The title dinuclear Fe(II) complex, [Fe(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, is centrosymmetric. Two sulfate anions bridge two Fe(II) cations to form the binuclear complex. Each Fe(II) cation is coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, two O a...

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Detalles Bibliográficos
Autores principales: Yang, Ming-Xing, Lin, Shen, Shen, Hui-Ying, Chen, Li-Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007828/
https://www.ncbi.nlm.nih.gov/pubmed/21588531
http://dx.doi.org/10.1107/S1600536810032496
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author Yang, Ming-Xing
Lin, Shen
Shen, Hui-Ying
Chen, Li-Juan
author_facet Yang, Ming-Xing
Lin, Shen
Shen, Hui-Ying
Chen, Li-Juan
author_sort Yang, Ming-Xing
collection PubMed
description The title dinuclear Fe(II) complex, [Fe(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, is centrosymmetric. Two sulfate anions bridge two Fe(II) cations to form the binuclear complex. Each Fe(II) cation is coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, two O atoms from two sulfate anions and two water mol­ecules in a distorted octa­hedral geometry. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. Weak π–π stacking is observed between parallel IP ring systems, the face-to-face separation being 3.428 (14) Å.
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spelling pubmed-30078282010-12-30 Di-μ-sulfato-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate Yang, Ming-Xing Lin, Shen Shen, Hui-Ying Chen, Li-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear Fe(II) complex, [Fe(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, is centrosymmetric. Two sulfate anions bridge two Fe(II) cations to form the binuclear complex. Each Fe(II) cation is coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, two O atoms from two sulfate anions and two water mol­ecules in a distorted octa­hedral geometry. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. Weak π–π stacking is observed between parallel IP ring systems, the face-to-face separation being 3.428 (14) Å. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007828/ /pubmed/21588531 http://dx.doi.org/10.1107/S1600536810032496 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Ming-Xing
Lin, Shen
Shen, Hui-Ying
Chen, Li-Juan
Di-μ-sulfato-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate
title Di-μ-sulfato-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate
title_full Di-μ-sulfato-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate
title_fullStr Di-μ-sulfato-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate
title_full_unstemmed Di-μ-sulfato-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate
title_short Di-μ-sulfato-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate
title_sort di-μ-sulfato-bis­[diaqua­(1h-imidazo[4,5-f][1,10]phenanthroline)iron(ii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007828/
https://www.ncbi.nlm.nih.gov/pubmed/21588531
http://dx.doi.org/10.1107/S1600536810032496
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