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6,6′-Dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate

In the crystal structure of the title compound, C(14)H(16)N(4)O(2) (2+)·2Cl(−)·CH(3)CN, weak inter­molecular N—H⋯Cl hydrogen bonds are found between the H atoms bound to the pyridine and amine N atoms and the chloride anions. The asymmetric unit consits of one half cationic mol­ecule which is locate...

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Detalles Bibliográficos
Autores principales: Hu, Hui-Ling, Cheng, Pei-Chi, Wu, Chia-Jun, Chen, Jhy-Der
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007829/
https://www.ncbi.nlm.nih.gov/pubmed/21588722
http://dx.doi.org/10.1107/S1600536810033519
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author Hu, Hui-Ling
Cheng, Pei-Chi
Wu, Chia-Jun
Chen, Jhy-Der
author_facet Hu, Hui-Ling
Cheng, Pei-Chi
Wu, Chia-Jun
Chen, Jhy-Der
author_sort Hu, Hui-Ling
collection PubMed
description In the crystal structure of the title compound, C(14)H(16)N(4)O(2) (2+)·2Cl(−)·CH(3)CN, weak inter­molecular N—H⋯Cl hydrogen bonds are found between the H atoms bound to the pyridine and amine N atoms and the chloride anions. The asymmetric unit consits of one half cationic mol­ecule which is located on a centre of inversion, one chloride anion in a general position and one half acetonitrile mol­ecule which is located on a twofold axis. Because of symmetry, the C—H hydrogens of the acetonitrile solvent mol­ecule are disordered over two orientations.
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spelling pubmed-30078292010-12-30 6,6′-Dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate Hu, Hui-Ling Cheng, Pei-Chi Wu, Chia-Jun Chen, Jhy-Der Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(14)H(16)N(4)O(2) (2+)·2Cl(−)·CH(3)CN, weak inter­molecular N—H⋯Cl hydrogen bonds are found between the H atoms bound to the pyridine and amine N atoms and the chloride anions. The asymmetric unit consits of one half cationic mol­ecule which is located on a centre of inversion, one chloride anion in a general position and one half acetonitrile mol­ecule which is located on a twofold axis. Because of symmetry, the C—H hydrogens of the acetonitrile solvent mol­ecule are disordered over two orientations. International Union of Crystallography 2010-08-25 /pmc/articles/PMC3007829/ /pubmed/21588722 http://dx.doi.org/10.1107/S1600536810033519 Text en © Hu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Hui-Ling
Cheng, Pei-Chi
Wu, Chia-Jun
Chen, Jhy-Der
6,6′-Dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate
title 6,6′-Dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate
title_full 6,6′-Dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate
title_fullStr 6,6′-Dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate
title_full_unstemmed 6,6′-Dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate
title_short 6,6′-Dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate
title_sort 6,6′-dimethyl-2,2′-[oxalylbis(aza­nedi­yl)]dipyridinium dichloride acetonitrile solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007829/
https://www.ncbi.nlm.nih.gov/pubmed/21588722
http://dx.doi.org/10.1107/S1600536810033519
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