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6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate
In the crystal structure of the title compound, C(14)H(16)N(4)O(2) (2+)·2Cl(−)·CH(3)CN, weak intermolecular N—H⋯Cl hydrogen bonds are found between the H atoms bound to the pyridine and amine N atoms and the chloride anions. The asymmetric unit consits of one half cationic molecule which is locate...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007829/ https://www.ncbi.nlm.nih.gov/pubmed/21588722 http://dx.doi.org/10.1107/S1600536810033519 |
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author | Hu, Hui-Ling Cheng, Pei-Chi Wu, Chia-Jun Chen, Jhy-Der |
author_facet | Hu, Hui-Ling Cheng, Pei-Chi Wu, Chia-Jun Chen, Jhy-Der |
author_sort | Hu, Hui-Ling |
collection | PubMed |
description | In the crystal structure of the title compound, C(14)H(16)N(4)O(2) (2+)·2Cl(−)·CH(3)CN, weak intermolecular N—H⋯Cl hydrogen bonds are found between the H atoms bound to the pyridine and amine N atoms and the chloride anions. The asymmetric unit consits of one half cationic molecule which is located on a centre of inversion, one chloride anion in a general position and one half acetonitrile molecule which is located on a twofold axis. Because of symmetry, the C—H hydrogens of the acetonitrile solvent molecule are disordered over two orientations. |
format | Text |
id | pubmed-3007829 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30078292010-12-30 6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate Hu, Hui-Ling Cheng, Pei-Chi Wu, Chia-Jun Chen, Jhy-Der Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(14)H(16)N(4)O(2) (2+)·2Cl(−)·CH(3)CN, weak intermolecular N—H⋯Cl hydrogen bonds are found between the H atoms bound to the pyridine and amine N atoms and the chloride anions. The asymmetric unit consits of one half cationic molecule which is located on a centre of inversion, one chloride anion in a general position and one half acetonitrile molecule which is located on a twofold axis. Because of symmetry, the C—H hydrogens of the acetonitrile solvent molecule are disordered over two orientations. International Union of Crystallography 2010-08-25 /pmc/articles/PMC3007829/ /pubmed/21588722 http://dx.doi.org/10.1107/S1600536810033519 Text en © Hu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hu, Hui-Ling Cheng, Pei-Chi Wu, Chia-Jun Chen, Jhy-Der 6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate |
title | 6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate |
title_full | 6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate |
title_fullStr | 6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate |
title_full_unstemmed | 6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate |
title_short | 6,6′-Dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate |
title_sort | 6,6′-dimethyl-2,2′-[oxalylbis(azanediyl)]dipyridinium dichloride acetonitrile solvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007829/ https://www.ncbi.nlm.nih.gov/pubmed/21588722 http://dx.doi.org/10.1107/S1600536810033519 |
work_keys_str_mv | AT huhuiling 66dimethyl22oxalylbisazanediyldipyridiniumdichlorideacetonitrilesolvate AT chengpeichi 66dimethyl22oxalylbisazanediyldipyridiniumdichlorideacetonitrilesolvate AT wuchiajun 66dimethyl22oxalylbisazanediyldipyridiniumdichlorideacetonitrilesolvate AT chenjhyder 66dimethyl22oxalylbisazanediyldipyridiniumdichlorideacetonitrilesolvate |