Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV)

The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol­ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl­pyrimidine-2-thiol­ate anions in a distorted SnS(2)C(2) tetra­hedral geometry. In...

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Detalles Bibliográficos
Autores principales: Shi, Yang, Zhang, Ru-Fen, Ma, Chun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007831/
https://www.ncbi.nlm.nih.gov/pubmed/21588562
http://dx.doi.org/10.1107/S1600536810030412
Descripción
Sumario:The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol­ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl­pyrimidine-2-thiol­ate anions in a distorted SnS(2)C(2) tetra­hedral geometry. In the two mol­ecules, the S—Sn—S bond angles are 87.70 (5) and 88.93 (4)°, while the C—Sn—C bond angles are 125.7 (3) and 125.9 (2)°. Weak C—H⋯N hydrogen bonding is present in the crystal structure.

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