Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV)

The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol­ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl­pyrimidine-2-thiol­ate anions in a distorted SnS(2)C(2) tetra­hedral geometry. In...

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Detalles Bibliográficos
Autores principales: Shi, Yang, Zhang, Ru-Fen, Ma, Chun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007831/
https://www.ncbi.nlm.nih.gov/pubmed/21588562
http://dx.doi.org/10.1107/S1600536810030412
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author Shi, Yang
Zhang, Ru-Fen
Ma, Chun-Lin
author_facet Shi, Yang
Zhang, Ru-Fen
Ma, Chun-Lin
author_sort Shi, Yang
collection PubMed
description The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol­ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl­pyrimidine-2-thiol­ate anions in a distorted SnS(2)C(2) tetra­hedral geometry. In the two mol­ecules, the S—Sn—S bond angles are 87.70 (5) and 88.93 (4)°, while the C—Sn—C bond angles are 125.7 (3) and 125.9 (2)°. Weak C—H⋯N hydrogen bonding is present in the crystal structure.
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spelling pubmed-30078312010-12-30 Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV) Shi, Yang Zhang, Ru-Fen Ma, Chun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol­ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl­pyrimidine-2-thiol­ate anions in a distorted SnS(2)C(2) tetra­hedral geometry. In the two mol­ecules, the S—Sn—S bond angles are 87.70 (5) and 88.93 (4)°, while the C—Sn—C bond angles are 125.7 (3) and 125.9 (2)°. Weak C—H⋯N hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007831/ /pubmed/21588562 http://dx.doi.org/10.1107/S1600536810030412 Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Yang
Zhang, Ru-Fen
Ma, Chun-Lin
Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV)
title Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV)
title_full Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV)
title_fullStr Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV)
title_full_unstemmed Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV)
title_short Bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(IV)
title_sort bis(4,6-dimethyl­pyrimidine-2-thiol­ato)dimethyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007831/
https://www.ncbi.nlm.nih.gov/pubmed/21588562
http://dx.doi.org/10.1107/S1600536810030412
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