Poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) N:O (3):O (4))(triphenyl­phosphine-κP)silver(I)]

In the title 1:1 silver(I) 4-carb­oxy­pyridine-3-carboxyl­ate adduct with triphenyl­phosphine, [Ag(C(7)H(4)NO(4))(C(18)H(15)P)](n), the carboxyl­ate anion bridges the phosphine-coordinated Ag atoms through its N and O atoms, generating a coordination polymer forming layers in the bc plane. The Ag at...

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Detalles Bibliográficos
Autores principales: Sadeghi, Omid, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007833/
https://www.ncbi.nlm.nih.gov/pubmed/21588554
http://dx.doi.org/10.1107/S1600536810033350
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author Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
author_facet Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
author_sort Sadeghi, Omid
collection PubMed
description In the title 1:1 silver(I) 4-carb­oxy­pyridine-3-carboxyl­ate adduct with triphenyl­phosphine, [Ag(C(7)H(4)NO(4))(C(18)H(15)P)](n), the carboxyl­ate anion bridges the phosphine-coordinated Ag atoms through its N and O atoms, generating a coordination polymer forming layers in the bc plane. The Ag atom exists in a distorted tetra­hedral geometry. The H atom of the carboxyl­ate is midway between two O atoms of the two carboxyl groups, thus forming a strong intra­molecular hydrogen bond.
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spelling pubmed-30078332010-12-30 Poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) N:O (3):O (4))(triphenyl­phosphine-κP)silver(I)] Sadeghi, Omid Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title 1:1 silver(I) 4-carb­oxy­pyridine-3-carboxyl­ate adduct with triphenyl­phosphine, [Ag(C(7)H(4)NO(4))(C(18)H(15)P)](n), the carboxyl­ate anion bridges the phosphine-coordinated Ag atoms through its N and O atoms, generating a coordination polymer forming layers in the bc plane. The Ag atom exists in a distorted tetra­hedral geometry. The H atom of the carboxyl­ate is midway between two O atoms of the two carboxyl groups, thus forming a strong intra­molecular hydrogen bond. International Union of Crystallography 2010-08-25 /pmc/articles/PMC3007833/ /pubmed/21588554 http://dx.doi.org/10.1107/S1600536810033350 Text en © Sadeghi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
Poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) N:O (3):O (4))(triphenyl­phosphine-κP)silver(I)]
title Poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) N:O (3):O (4))(triphenyl­phosphine-κP)silver(I)]
title_full Poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) N:O (3):O (4))(triphenyl­phosphine-κP)silver(I)]
title_fullStr Poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) N:O (3):O (4))(triphenyl­phosphine-κP)silver(I)]
title_full_unstemmed Poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) N:O (3):O (4))(triphenyl­phosphine-κP)silver(I)]
title_short Poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) N:O (3):O (4))(triphenyl­phosphine-κP)silver(I)]
title_sort poly[(μ(3)-4-carb­oxy­pyridine-3-carboxyl­ato-κ(3) n:o (3):o (4))(triphenyl­phosphine-κp)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007833/
https://www.ncbi.nlm.nih.gov/pubmed/21588554
http://dx.doi.org/10.1107/S1600536810033350
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AT ngseikweng polym34carboxypyridine3carboxylatok3no3o4triphenylphosphinekpsilveri

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