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2-Hydroxy-N-(3-nitrophenyl)benzamide
In the crystal structure of title compound, C(13)H(10)N(2)O(4), as expected, the nitro- and hydroxy-substituted benzene rings are planar with r. m. s. deviations of 0.0037 and 0.0014 Å, respectively, but are twisted slightly relative to each other, making a dihedral angle of 12.23 (7)°. The nitro g...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007834/ https://www.ncbi.nlm.nih.gov/pubmed/21588758 http://dx.doi.org/10.1107/S1600536810031910 |
Sumario: | In the crystal structure of title compound, C(13)H(10)N(2)O(4), as expected, the nitro- and hydroxy-substituted benzene rings are planar with r. m. s. deviations of 0.0037 and 0.0014 Å, respectively, but are twisted slightly relative to each other, making a dihedral angle of 12.23 (7)°. The nitro group is only slightly twisted [by 2.71 (16)°] with respect to its parent ring. An intramolecular N—H⋯O hydrogen bond forms an S(6) ring motif. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds build up sheets parallel to the ab plane. Futhermore, weak π–π interactions [centroid–centroid distances = 3.7150 (8) 3.7342 (6) and 3.9421 (8) Å] between the rings yield a three-dimensional network. |
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