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2-Hy­droxy-N-(3-nitro­phen­yl)benzamide

In the crystal structure of title compound, C(13)H(10)N(2)O(4), as expected, the nitro- and hy­droxy-substituted benzene rings are planar with r. m. s. deviations of 0.0037 and 0.0014 Å, respectively, but are twisted slightly relative to each other, making a dihedral angle of 12.23 (7)°. The nitro g...

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Detalles Bibliográficos
Autores principales: Raza, Abdul Rauf, Nisar, Bushra, Tahir, M. Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007834/
https://www.ncbi.nlm.nih.gov/pubmed/21588758
http://dx.doi.org/10.1107/S1600536810031910
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author Raza, Abdul Rauf
Nisar, Bushra
Tahir, M. Nawaz
author_facet Raza, Abdul Rauf
Nisar, Bushra
Tahir, M. Nawaz
author_sort Raza, Abdul Rauf
collection PubMed
description In the crystal structure of title compound, C(13)H(10)N(2)O(4), as expected, the nitro- and hy­droxy-substituted benzene rings are planar with r. m. s. deviations of 0.0037 and 0.0014 Å, respectively, but are twisted slightly relative to each other, making a dihedral angle of 12.23 (7)°. The nitro group is only slightly twisted [by 2.71 (16)°] with respect to its parent ring. An intra­molecular N—H⋯O hydrogen bond forms an S(6) ring motif. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds build up sheets parallel to the ab plane. Futhermore, weak π–π inter­actions [centroid–centroid distances = 3.7150 (8) 3.7342 (6) and 3.9421 (8) Å] between the rings yield a three-dimensional network.
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spelling pubmed-30078342010-12-30 2-Hy­droxy-N-(3-nitro­phen­yl)benzamide Raza, Abdul Rauf Nisar, Bushra Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of title compound, C(13)H(10)N(2)O(4), as expected, the nitro- and hy­droxy-substituted benzene rings are planar with r. m. s. deviations of 0.0037 and 0.0014 Å, respectively, but are twisted slightly relative to each other, making a dihedral angle of 12.23 (7)°. The nitro group is only slightly twisted [by 2.71 (16)°] with respect to its parent ring. An intra­molecular N—H⋯O hydrogen bond forms an S(6) ring motif. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds build up sheets parallel to the ab plane. Futhermore, weak π–π inter­actions [centroid–centroid distances = 3.7150 (8) 3.7342 (6) and 3.9421 (8) Å] between the rings yield a three-dimensional network. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007834/ /pubmed/21588758 http://dx.doi.org/10.1107/S1600536810031910 Text en © Raza et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Raza, Abdul Rauf
Nisar, Bushra
Tahir, M. Nawaz
2-Hy­droxy-N-(3-nitro­phen­yl)benzamide
title 2-Hy­droxy-N-(3-nitro­phen­yl)benzamide
title_full 2-Hy­droxy-N-(3-nitro­phen­yl)benzamide
title_fullStr 2-Hy­droxy-N-(3-nitro­phen­yl)benzamide
title_full_unstemmed 2-Hy­droxy-N-(3-nitro­phen­yl)benzamide
title_short 2-Hy­droxy-N-(3-nitro­phen­yl)benzamide
title_sort 2-hy­droxy-n-(3-nitro­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007834/
https://www.ncbi.nlm.nih.gov/pubmed/21588758
http://dx.doi.org/10.1107/S1600536810031910
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