Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)]

In the title polymeric Cu(I) compound, [Cu(2)Br(2)(C(12)H(10)N(2))](n), the Cu cation is coordinated by an N atom from the 1,2-bis­(4-pyrid­yl)ethene ligand and three Br(−) anions in a distorted tetra­hedral CuBr(3)N coordination geometry. Each Br(−) anion bridges three Cu cations related by inversi...

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Detalles Bibliográficos
Autores principales: Shen, Fwu Ming, Lush, Shie Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007837/
https://www.ncbi.nlm.nih.gov/pubmed/21588492
http://dx.doi.org/10.1107/S1600536810030734
Descripción
Sumario:In the title polymeric Cu(I) compound, [Cu(2)Br(2)(C(12)H(10)N(2))](n), the Cu cation is coordinated by an N atom from the 1,2-bis­(4-pyrid­yl)ethene ligand and three Br(−) anions in a distorted tetra­hedral CuBr(3)N coordination geometry. Each Br(−) anion bridges three Cu cations related by inversion centers, forming a stair-like polymeric chain along the a axis, and the terminal N atoms of the 1,2-bis­(4-pyrid­yl)ethene ligand, located across an inversion center, coordinate the Cu cations from neighboring chains, forming polymeric sheets.

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