Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)]

In the title polymeric Cu(I) compound, [Cu(2)Br(2)(C(12)H(10)N(2))](n), the Cu cation is coordinated by an N atom from the 1,2-bis­(4-pyrid­yl)ethene ligand and three Br(−) anions in a distorted tetra­hedral CuBr(3)N coordination geometry. Each Br(−) anion bridges three Cu cations related by inversi...

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Detalles Bibliográficos
Autores principales: Shen, Fwu Ming, Lush, Shie Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007837/
https://www.ncbi.nlm.nih.gov/pubmed/21588492
http://dx.doi.org/10.1107/S1600536810030734
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author Shen, Fwu Ming
Lush, Shie Fu
author_facet Shen, Fwu Ming
Lush, Shie Fu
author_sort Shen, Fwu Ming
collection PubMed
description In the title polymeric Cu(I) compound, [Cu(2)Br(2)(C(12)H(10)N(2))](n), the Cu cation is coordinated by an N atom from the 1,2-bis­(4-pyrid­yl)ethene ligand and three Br(−) anions in a distorted tetra­hedral CuBr(3)N coordination geometry. Each Br(−) anion bridges three Cu cations related by inversion centers, forming a stair-like polymeric chain along the a axis, and the terminal N atoms of the 1,2-bis­(4-pyrid­yl)ethene ligand, located across an inversion center, coordinate the Cu cations from neighboring chains, forming polymeric sheets.
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spelling pubmed-30078372010-12-30 Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)] Shen, Fwu Ming Lush, Shie Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric Cu(I) compound, [Cu(2)Br(2)(C(12)H(10)N(2))](n), the Cu cation is coordinated by an N atom from the 1,2-bis­(4-pyrid­yl)ethene ligand and three Br(−) anions in a distorted tetra­hedral CuBr(3)N coordination geometry. Each Br(−) anion bridges three Cu cations related by inversion centers, forming a stair-like polymeric chain along the a axis, and the terminal N atoms of the 1,2-bis­(4-pyrid­yl)ethene ligand, located across an inversion center, coordinate the Cu cations from neighboring chains, forming polymeric sheets. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007837/ /pubmed/21588492 http://dx.doi.org/10.1107/S1600536810030734 Text en © Shen and Lush 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Fwu Ming
Lush, Shie Fu
Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)]
title Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)]
title_full Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)]
title_fullStr Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)]
title_full_unstemmed Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)]
title_short Poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]-di-μ(3)-bromido-dicopper(I)]
title_sort poly[[μ(2)-1,2-bis­(4-pyrid­yl)ethene-κ(2) n:n′]-di-μ(3)-bromido-dicopper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007837/
https://www.ncbi.nlm.nih.gov/pubmed/21588492
http://dx.doi.org/10.1107/S1600536810030734
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AT lushshiefu polym212bis4pyridylethenek2nndim3bromidodicopperi

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