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2-Amino-5-bromopyridinium 3-carboxy-4-hydroxybenzenesulfonate
The asymmetric unit of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(5)O(6)S(−), contains two independent 2-amino-5-bromopyridinium cations and two independent 3-carboxy-4-hydroxybenzenesulfonate anions. The hydroxy and carboxyl groups of the anions are involved in intramolecular O—H⋯O hydrogen bo...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007841/ https://www.ncbi.nlm.nih.gov/pubmed/21588738 http://dx.doi.org/10.1107/S1600536810033908 |
Sumario: | The asymmetric unit of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(5)O(6)S(−), contains two independent 2-amino-5-bromopyridinium cations and two independent 3-carboxy-4-hydroxybenzenesulfonate anions. The hydroxy and carboxyl groups of the anions are involved in intramolecular O—H⋯O hydrogen bonds, which generate S(6) ring motifs. In the crystal structure, the ions are linked by N—H⋯O and O—H⋯O hydrogen bonds into a two-dimensional network parallel to (110). Adjacent networks are linked via C—H⋯O hydrogen bonds. |
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