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2-Amino-5-bromo­pyridinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate

The asymmetric unit of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(5)O(6)S(−), contains two independent 2-amino-5-bromo­pyridinium cations and two independent 3-carb­oxy-4-hy­droxy­benzene­sulfonate anions. The hy­droxy and carboxyl groups of the anions are involved in intra­molecular O—H⋯O hydrogen bo...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007841/
https://www.ncbi.nlm.nih.gov/pubmed/21588738
http://dx.doi.org/10.1107/S1600536810033908
Descripción
Sumario:The asymmetric unit of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(5)O(6)S(−), contains two independent 2-amino-5-bromo­pyridinium cations and two independent 3-carb­oxy-4-hy­droxy­benzene­sulfonate anions. The hy­droxy and carboxyl groups of the anions are involved in intra­molecular O—H⋯O hydrogen bonds, which generate S(6) ring motifs. In the crystal structure, the ions are linked by N—H⋯O and O—H⋯O hydrogen bonds into a two-dimensional network parallel to (110). Adjacent networks are linked via C—H⋯O hydrogen bonds.