(E)-Methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate

The title compound, C(9)H(8)Br(2)N(2)O(3), crystallizes with two very similar independent mol­ecules in the asymmetric unit, each of which adopts a trans configuration with respect to the C=N bond. Intra­molecular O—H⋯N hydrogen bonds are observed in each independent mol­ecule. In the crystal struct...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Liu, Songhui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007842/
https://www.ncbi.nlm.nih.gov/pubmed/21588736
http://dx.doi.org/10.1107/S1600536810033799
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author Lv, Lu-Ping
Liu, Songhui
author_facet Lv, Lu-Ping
Liu, Songhui
author_sort Lv, Lu-Ping
collection PubMed
description The title compound, C(9)H(8)Br(2)N(2)O(3), crystallizes with two very similar independent mol­ecules in the asymmetric unit, each of which adopts a trans configuration with respect to the C=N bond. Intra­molecular O—H⋯N hydrogen bonds are observed in each independent mol­ecule. In the crystal structure, mol­ecules are linked into chains propagating along [010] by N—H⋯O and C—H⋯O hydrogen bonds. In addition, C—H⋯π inter­actions stabilize the structure.
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spelling pubmed-30078422010-12-30 (E)-Methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate Lv, Lu-Ping Liu, Songhui Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(8)Br(2)N(2)O(3), crystallizes with two very similar independent mol­ecules in the asymmetric unit, each of which adopts a trans configuration with respect to the C=N bond. Intra­molecular O—H⋯N hydrogen bonds are observed in each independent mol­ecule. In the crystal structure, mol­ecules are linked into chains propagating along [010] by N—H⋯O and C—H⋯O hydrogen bonds. In addition, C—H⋯π inter­actions stabilize the structure. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007842/ /pubmed/21588736 http://dx.doi.org/10.1107/S1600536810033799 Text en © Lv and Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Liu, Songhui
(E)-Methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate
title (E)-Methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate
title_full (E)-Methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate
title_fullStr (E)-Methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate
title_full_unstemmed (E)-Methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate
title_short (E)-Methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate
title_sort (e)-methyl 3-(3,5-dibromo-2-hy­droxy­benzyl­idene)carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007842/
https://www.ncbi.nlm.nih.gov/pubmed/21588736
http://dx.doi.org/10.1107/S1600536810033799
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