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2-(2,3-Dimethylphenyl)-1H-isoindole-1,3(2H)-dione
In the title compound, C(16)H(13)NO(2), the 2,3-dimethylphenyl group and the 1H-isoindole-1,3(2H)-dione group are essentially planar, with r.m.s. deviations of 0.006 and 0.013 Å, respectively, and are oriented at an angle of 78.19 (3)° with respect to each other. In the crystal, weak C—H⋯O interac...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007846/ https://www.ncbi.nlm.nih.gov/pubmed/21588762 http://dx.doi.org/10.1107/S1600536810033386 |
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author | Tariq, Muhammad Ilyas Noreen, Tanzeela Tahir, M. Nawaz Ahmad, Shahbaz Fayyaz-ur-Rehman, Muhammad |
author_facet | Tariq, Muhammad Ilyas Noreen, Tanzeela Tahir, M. Nawaz Ahmad, Shahbaz Fayyaz-ur-Rehman, Muhammad |
author_sort | Tariq, Muhammad Ilyas |
collection | PubMed |
description | In the title compound, C(16)H(13)NO(2), the 2,3-dimethylphenyl group and the 1H-isoindole-1,3(2H)-dione group are essentially planar, with r.m.s. deviations of 0.006 and 0.013 Å, respectively, and are oriented at an angle of 78.19 (3)° with respect to each other. In the crystal, weak C—H⋯O interactions link the molecules, forming a zigzag chain parallel to the b axis. Futhermore, C—H⋯π interactions are present between the C—H group of isoindole and the 2,3-dimethylphenyl benzene ring. The H atoms of the ortho-methyl group are statistically disordered over two positions. Such disorder might be related to the antagonism between intramolecular steric repulsions and intermolecular C—H⋯O interactions. |
format | Text |
id | pubmed-3007846 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30078462010-12-30 2-(2,3-Dimethylphenyl)-1H-isoindole-1,3(2H)-dione Tariq, Muhammad Ilyas Noreen, Tanzeela Tahir, M. Nawaz Ahmad, Shahbaz Fayyaz-ur-Rehman, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(13)NO(2), the 2,3-dimethylphenyl group and the 1H-isoindole-1,3(2H)-dione group are essentially planar, with r.m.s. deviations of 0.006 and 0.013 Å, respectively, and are oriented at an angle of 78.19 (3)° with respect to each other. In the crystal, weak C—H⋯O interactions link the molecules, forming a zigzag chain parallel to the b axis. Futhermore, C—H⋯π interactions are present between the C—H group of isoindole and the 2,3-dimethylphenyl benzene ring. The H atoms of the ortho-methyl group are statistically disordered over two positions. Such disorder might be related to the antagonism between intramolecular steric repulsions and intermolecular C—H⋯O interactions. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007846/ /pubmed/21588762 http://dx.doi.org/10.1107/S1600536810033386 Text en © Tariq et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tariq, Muhammad Ilyas Noreen, Tanzeela Tahir, M. Nawaz Ahmad, Shahbaz Fayyaz-ur-Rehman, Muhammad 2-(2,3-Dimethylphenyl)-1H-isoindole-1,3(2H)-dione |
title | 2-(2,3-Dimethylphenyl)-1H-isoindole-1,3(2H)-dione |
title_full | 2-(2,3-Dimethylphenyl)-1H-isoindole-1,3(2H)-dione |
title_fullStr | 2-(2,3-Dimethylphenyl)-1H-isoindole-1,3(2H)-dione |
title_full_unstemmed | 2-(2,3-Dimethylphenyl)-1H-isoindole-1,3(2H)-dione |
title_short | 2-(2,3-Dimethylphenyl)-1H-isoindole-1,3(2H)-dione |
title_sort | 2-(2,3-dimethylphenyl)-1h-isoindole-1,3(2h)-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007846/ https://www.ncbi.nlm.nih.gov/pubmed/21588762 http://dx.doi.org/10.1107/S1600536810033386 |
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