2-Hy­droxy-11-methyl-16-[(E)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione

In the title compound, C(32)H(30)N(2)O(3), the piperidin-4-one and the two fused pyrrolidine rings adopt envelope conformations. The two methyl­phenyl rings are oriented at dihedral angle of 20.36 (7) and 56.24 (7)°, respectively, with respect to the indanone ring system. In the crystal structure, i...

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Detalles Bibliográficos
Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Ali, Mohamed Ashraf, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007847/
https://www.ncbi.nlm.nih.gov/pubmed/21588710
http://dx.doi.org/10.1107/S1600536810033064
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author Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Kumar, Raju Suresh
collection PubMed
description In the title compound, C(32)H(30)N(2)O(3), the piperidin-4-one and the two fused pyrrolidine rings adopt envelope conformations. The two methyl­phenyl rings are oriented at dihedral angle of 20.36 (7) and 56.24 (7)°, respectively, with respect to the indanone ring system. In the crystal structure, inter­molecular O—H⋯N and C—H⋯O hydrogen bonds link the mol­ecules into chains propagating along [001]. Weak C—H⋯π inter­actions are also observed.
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spelling pubmed-30078472010-12-30 2-Hy­droxy-11-methyl-16-[(E)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione Kumar, Raju Suresh Osman, Hasnah Ali, Mohamed Ashraf Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(30)N(2)O(3), the piperidin-4-one and the two fused pyrrolidine rings adopt envelope conformations. The two methyl­phenyl rings are oriented at dihedral angle of 20.36 (7) and 56.24 (7)°, respectively, with respect to the indanone ring system. In the crystal structure, inter­molecular O—H⋯N and C—H⋯O hydrogen bonds link the mol­ecules into chains propagating along [001]. Weak C—H⋯π inter­actions are also observed. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007847/ /pubmed/21588710 http://dx.doi.org/10.1107/S1600536810033064 Text en © Kumar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Yeap, Chin Sing
Fun, Hoong-Kun
2-Hy­droxy-11-methyl-16-[(E)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title 2-Hy­droxy-11-methyl-16-[(E)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_full 2-Hy­droxy-11-methyl-16-[(E)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_fullStr 2-Hy­droxy-11-methyl-16-[(E)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_full_unstemmed 2-Hy­droxy-11-methyl-16-[(E)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_short 2-Hy­droxy-11-methyl-16-[(E)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_sort 2-hy­droxy-11-methyl-16-[(e)-4-methyl­benzyl­idene]-13-(4-methyl­phen­yl)-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007847/
https://www.ncbi.nlm.nih.gov/pubmed/21588710
http://dx.doi.org/10.1107/S1600536810033064
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