Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) 3.5-hydrate

In the title complex, [Mn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Mn(II) cation is six-coordinated by two N,O-bidentate H(2)pimda(−) ligands (H(2)pimda(−) = 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate) and two water mol­ecules in a distorted octa­hedral environment. The complete solid-stat...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Shi-Jie, Miao, Dong-Liang, Song, Wen-Dong, Li, Shi-Hong, Yan, Jian-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007852/
https://www.ncbi.nlm.nih.gov/pubmed/21588510
http://dx.doi.org/10.1107/S1600536810031612
Descripción
Sumario:In the title complex, [Mn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Mn(II) cation is six-coordinated by two N,O-bidentate H(2)pimda(−) ligands (H(2)pimda(−) = 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate) and two water mol­ecules in a distorted octa­hedral environment. The complete solid-state structure can be described as a three-dimensional supra­molecular framework stabilized by a wide range of O—H⋯O and N—H⋯O hydrogen bonds. The propyl groups of H(2)pimda(−) are disordered over two sets of sites with refined occupancies of 0.759 (5):0.241 (5) and 0.545 (7):0.455 (7).

Ejemplares similares