Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate

The asymmetric unit of the title compound, [Ni(C(10)H(8)N(2))(3)][Mo(6)O(19)], consists of one complex [(Ni(C(10)H(8)N(2))(3)](2+) cation and one Lindqvist-type [Mo(6)O(19)](2−) polyanion. The Ni(2+) ion is in a distorted octa­hedral coordination by six N atoms from three chelating 2,2′-bipyridine l...

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Detalles Bibliográficos
Autores principales: Fan, Liming, Wei, Peihai, Pang, Shuming, Zhang, Xiutang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007854/
https://www.ncbi.nlm.nih.gov/pubmed/21588523
http://dx.doi.org/10.1107/S1600536810032058
Descripción
Sumario:The asymmetric unit of the title compound, [Ni(C(10)H(8)N(2))(3)][Mo(6)O(19)], consists of one complex [(Ni(C(10)H(8)N(2))(3)](2+) cation and one Lindqvist-type [Mo(6)O(19)](2−) polyanion. The Ni(2+) ion is in a distorted octa­hedral coordination by six N atoms from three chelating 2,2′-bipyridine ligands. The Lindqvist-type anion exhibits the characteristic Mo—O bond-length distribution, with the shortest bonds being the Mo—O(terminal) bonds [mean = 1.679 (2) Å] and the longest being those to the central O atom [mean = 2.318 (7) Å]. A number of C—H⋯O inter­actions contribute to the crystal packing.

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